全自动消解测定土壤沉积物中的有机碳.pdfVIP

环境工程 152 Environmental Engineering 全自动消解测定土壤/沉积物中的有机碳* 李国傲何咏陈雪李烨 (北京市环境保护科学研究院国家城市环境污染控制工程技术研究中心，北京 100037 ) 摘要:基于传统方法重络酸饵氧化-分光光度法的原理，应用全自动消解仪测定土壤/沉积物中的有机碳。通过优化 反应条件，将复杂的前处理过程自动化，可同时分析大批量样品。实验结果表明:该方法在 0-24 mg 线性关系良好， 3 相关系数大于 0.999 4% ;高浓度和低浓度的加标回收率分 测定高、中、低 种浓度的样品，其相对标准偏差均小于 0 别为 95.9% -106% 和 9 1. 7% - 105% 。当取样量为 0.5000 g 时，检出限为 0.05869岛，方法指标满足对样品的准确分 析。对比现有实验方法，该方法具有高效、节能、准确、安全等优点c 关键词:全自动消解;土壤;沉积物;有机碳 DOI: 10. 13205/j. hjgc. 201605033 DETERMINATION OF ORGANIC CARBON IN SOIL/SEDIMENTS BY AUTOMATIC DIGESTION LI Guo-ao , HE Yong , CHEN Xue , LI Ye (National Engineering Research Center of Urban Environmental Pollution Control , Beijing Municipal Research Institute of Environmental Protection , Beijing 100037 , China) Abstract: This research based on the principle of traditional method: Potassium dichromate oxidation-spectrophotometry. Automatic digestion was applied in determination of organic carbon in the soils/sediments. The reaction conditions were optimized and the complex pretreatments were automated to analyze quantities of samples at the same time. The results showed that this method had good linear relationship between 0 - 24mg which correlation coefficient was greater than o. 999. The relative standard deviations of three different concentrations were less than 4%. Standard addition recoveηof high and low concentration ranged from 95.9% to 106% and 9 1. 7% to 95.9% respectively. When the sampling quantity was 0.5000 g , the detection