不同液化条件对毛竹粉多元醇液化产物分子量的影响 - 江西农业大学学报.pdfVIP

2010, 32( 6) : 1191- 1194 http: / / xuebao. jxau. edu. cn A cta A gr icu turae Un iversitatis J iangx iensis E - m ai: ndxb7775@ sina. com 张金萍, 杜孟浩, 王敬文 ( , 311400) : PEG400 /G ycerin, , : 21 41, M w M w /M n ; 2% 3% , M w M w /M n , 4% ; 130 140 , M M /M , w w n 150 , 160 ; , M w M w /M n 120 m in : ; ; ; : TQ351. 0 : A : 1000 - 22 86( 20 10) 06- 119 1- 04 EffectsofVariousReactionParametersduringBambooPowderLiquefaction with PolyhydricAlcoholsonMolecularWeight and Polydispersity ZHANG J inp ing, DU M enghao, WANG J ingw en ( Research Institute o f Sub trop ica F orestry, Ch inese A cadem y of Forestry, Fuyang 3 11400, China) Abstract:T he effects o f the iquefy ing condit ion on m o ecu ar w eigh t of bamboo powder iquefaction prod uct wh ich iquefy ing w ith po ya coho 400 and g ycerin as ique fier and su furic ac id as cata yst w ere studied. Expermi ents show ed that : the w e ight - average m o ecu ar w eight (M w ) and po yd ispersity (M w /M n ) de creased first y and increased w ith enhancing of H 2 SO4 unt i H 2 SO4 concen trat ion reached 4% whereM w and po ydispersity decreased cont inuou s y. A s the ratio o f iqu id to so id increased, Mw and po yd ispersity de creased cont inuous y; the w e igh t- average m o ecu ar w eight (M w ) and po yd ispersity (M w /M n ) of copo ym er decreased first y and increased when the reaction tem perature reached 150 and then decreased