催化剂制备聚己内酯.pdf

Inorganic Chemistry Communications 14 (2011) 271–275 Contents lists available at ScienceDirect Inorganic Chemistry Communications journal homepage: www.el /l oca te/ inoche Reactions of 4-methylidene-bis(1-phenyl-3-methylpyrazol-5-one) with trimethylaluminum: Synthesis, structure and catalysis for the ring-opening polymerization of ε-caprolactone Chen-Yen Tsai a, Chen-Yu Li a, Chia-Her Lin a, Bor-Hunn Huang b, Bao-Tsan Ko a,⁎ a Department of Chemistry, Chung Yuan Christian University, Chung-Li 32023, Taiwan b Department of Chemistry, National Chung-Hsing University, Taichung 402, Taiwan a r t i c l e i n f o a b s t r a c t Article history: Aluminum complexes bearing ligand O,O-bidentate dipyrazolate are synthesized and structurally character- Received 14 September 2010 ized. The reaction of 4-methylidene-bis(1-phenyl-3-methylpyrazol-5-one) (MBP-H) with AlMe3 (1.2 molar Accepted 4 November 2010 equiv) in toluene yields [(MBP)AlMe2 ] (1) as the four-coordinate monomeric aluminum complex. Tri-adduct Available online 22 November 2010 complex [Al(MBP) ] (2) results from treatment of AlMe with MBP-H (3 molar equiv) in toluene in a high 3 3 yield. In the presence of 9-anthracenemethanol, mono-adduct aluminum complex 1 catalyzes efficiently the Keywords: ring-opening polymerization of ε-caprolactone (ε-CL) in a control