化学镀ni-p 镀层的防腐蚀后处理工艺研究.pdf

化学镀Ni-P 镀层的防腐蚀后处理工艺研究 刘光明 刘 斌 南昌航空大学材料科学与工程学院 南昌 330063 摘 要： 钢铁基体上制备化学镀Ni-P 镀层后，分别采用γ-氨丙基三乙氧基硅烷(3-APTS) ，硬脂酸和3-APTS/ 硬脂酸对镀层进行防腐蚀后处理，利用点滴法、贴滤纸法、接触角测量、盐水浸渍实验法和电化学测试研 究了镀层耐蚀性的变化，比较了各工艺的后处理效果。结果表明：3 种后处理工艺都能提高化学镀Ni-P 镀 层的抗氧化性和耐蚀性，经3-APTS/硬脂酸复合处理后的镀层耐蚀性要优于3-APTS 和硬脂酸的单一处理， 镀层外观都没有明显变化。同时对缓蚀机理进行了分析。 关键词：化学镀Ni-P 镀层 3-APTS 硬脂酸 复合处理 耐蚀性 1 中图分类号：xxxxxx 文献标识码：A 文章编号：xxxx-xxxx(xxxx)xx-xxxx-xx v 5 Post-treatment processes for corrosion resistance on the electroless 0 4 0 Ni-P coating 0 . 1 LIU Guangming, LIU Bin 1 6 School of Materials Science and Engineering,Nanchang Hangkong University, Nanchang 3300 63, 1 0 2 Abstract ： post-treatment methods for corrosion resistance with γ-aminopropyl-triethoxy silane : v (3-APTS), stearic acid and compound of the both on the electroless Ni-P coating of steel substrate i X a were investigated by spot test, filter paper method, contant angle measurement, salt water n i immersion test and electrochemical measurements. Throught comparing corrosion resisting h c properties, the results showed: the three methods all can increase corrosion resistance of the nickel coating, corrosion resistance of the nickel coating compound post-treated by 3-APTS/stearic acid is superior to single post-treated by 3-APTS or stearic acid，there are all no change in the appearance of the nickel coating after post-treated. At the same time. the mechanism of inhibition were discussed in detail. Key words: electroless Ni-P coating, 3-APTS, stearic acid, compound treatm