无定形氧化铁-胡敏酸复合胶体对Cu^2＋的吸附特征.pdfVIP

中国环境科学 2007，27(6)：752-756 China Environmental Science 无定形氧化铁一胡敏酸复合胶体对Cu2+的吸附特征 王 强 ，魏世强 ，黄玉明 (1．西南大学资源环境学院，重庆市农业资源与环境研究重点实验室，重庆400716： 2．西南大学化学化工学院，重庆 400715) 摘要：采用Cu2+选择电极研究了不同pH值条件下胡敏酸fttA)、无定形Fe203、HA—Fe2o3复合胶体对Cu2+的等温吸附规律．结果表明，随 着 pH值的升高，3种胶体饱和吸附量和吸附平衡常数均增大，有利于吸附的进行．HA和无定形Fe2O3等温吸附Cu2 的4种拟合方程 中，Langmuir方程整体拟合效果最佳，其次为对数方程和Freundl~h方程Linear方程较差．HA—Fe203复合胶体等温吸附Cu 的4种拟合方 程均达到显著相关．在相同pH值条件下，无定形Fe2O3对Cu2+吸附量最小，复合胶体次之，HA 胶体最大；而且，无定形Fe203和复合胶体的饱 和吸附量之和小于HA胶体． 关键词：无定形氧化铁一胡敏酸复合胶体；Cu ；等温吸附 中图分类号：X131．2 文献标识码：A 文章编号：1000—6923(2007)06—0752-05 Adsorption characteristics of amorphous Fe203 and humic acid complex colloid to Cu 十．WANG Qiang ’．WEI Shi—qiang ，HUANG Yu—ming2(1．Chongqing Key Laboratory of Agricultural Resources and Environment，College of Resources and Environm ent，Southwest University,Chongqing 400716，China；2．College of Chemistry and Chemical Engineering Southwest University,Chongqing 400715，China)．China EnvironmentalScience，2007，27(6)：752-756 Abstract：The isothermal adsorption characteristics ofhumic acid colloid(HA)，amorphous Fe203 colloid,and HA —Fe203 complex colloid to Cu2 at different acidities were studied by using Cu2 selective electrode ． The maximum adsorption amounts( ax)and adsorption equilibrium constants( of three colloid were all increased with pH value increasing,and thus high pH Was beneficial to the adsorption process．The adsorption behaviors of HA and am orphous Fe203 colloid to Cu2 could be well described by Langmuir equation and then logarithm equation，Freundlich equation，and linear ， equation．while the adsorption behaviors of HA-Fe203 complex colloid to Cu could be well described by the four isothermal adsorption equations．At the same pH，the order of the adsorption amount obtained by the three colloids Was am orphous Fe203the complex colloid