锂硫电池硫碳复合正极材料的研究.pdfVIP

摘 要 硫由于具有较大的理论能量密度和理论比容量，成为最具发展潜力的锂二次 电池的正极材料。然而，锂硫电池硫正极材料也有它固有的缺陷，如多硫化物的 溶解，体积的扩张，及过硫化锂，硫化锂，硫的导电性差。这些缺点影响了锂硫 电池的大规模的实际应用。 为了解决锂硫电池面临的诸多问题，本论文提出了一个概念性的新方法。首 先通过化学方法将硫包覆在多壁碳纳米管的表面，制备硫碳复合材料。通过四氟 硼酸重氮盐的自发聚合反应形成导电聚苯层原位包覆硫碳纳米管（MWCNT ）核 壳结构。导电聚苯薄膜不仅能够阻止活性物质硫的溶解，还能够缩小锂离子传输 到反应位置的距离。这种架构结构在锂化过程中能够容纳硫电极的体积的扩张， 从而改善了锂硫电池的循环性能和倍率性能。在 0.1C 倍率下，初始放电容量高 达1491.3mAh/g ，并且经过75 次循环后放电容量仍然保持在1015.6 mAh/g。 关键词：硫 多壁碳纳米管 四氟硼酸重氮盐 锂硫电池 导电聚合物 Abstract Lithium-sulfur batteries have attracted particular interest due to their advantages, such as large theoretical capacity (1675 mAh/g), high specific energy density (2600 Wh/Kg). However, the lithium-sulfur batteries suffers the intrinsic defect problems of the dissolution of intermediate lithium polysulfide products Li S (4≤ n ≤8), 2 n volumetric expansion and the poor conductivity of sulfur and Li S and/or Li S 2 2 2 species, prevent it for large-scale application. In this paper, a new approachwas proposed to address aforementioned challenges. First, the sulfur surfaces of the carbon nanotubes was coated by chemical reactions,then the sulfue/carbon composite material was prepared, a novel conducting polymer polyphenylene is used to in situ wrap theMWCNT-core/Sulfur-shell composite rely on the spontaneous polymerization reaction process of benzenediazonium tetrafluoroborate (ArN2+ BF4-).The conductive polymer thin layer can not only prevent the dissolution of active sulfur, but also shorten lithium ion transfer to reaction site. Polyphenylene/S/MWCNTs,