Cd0．8Mn0．2Te晶体生长及结晶质量评价.pdfVIP

第36卷 第6期 人 工 晶 体 学 报 Vo1．36 No．6 2007年l2月 JOURNAL OF SYNTHETIC CRYSTALS December．20o7 CIlo．8 MIlo．2 Te晶体生长及结晶质量评价 杨 波，介万奇，张继军，白旭旭 (西北工业大学材料学院，西安710072) 摘要：采用垂直布里奇曼法生长了尺寸为630 mm×120 mm的Cd Mn。 Te晶锭。采用x射线粉末衍射及x射线双 晶摇摆曲线分析了晶体的结构与结晶质量，结果显示所生长的晶体为单一立方闪锌矿结构，半峰宽为47．2arcsec，结 晶质量良好。采用化学腐蚀方法显示了晶体中的多种缺陷，包括位错，1’e夹杂和孪晶。采用光学显微镜，扫描电镜和 X射线能谱仪对缺陷形态和分布进行了研究。结果表明，晶体中位错密度在l0 ～10。cm 之间。晶体局部存在 夹 杂相，尺寸为1～5p,m。晶体中孪晶主要以共格孪晶存在。并提出了缺陷形成的原因和减少缺陷的方法。 关键词：Cao Mn Te；X射线粉末衍射；X射线双晶摇摆曲线；位错；Te夹杂；孪晶 图分类号：078 文献标识码：A 文章编号：1000-985X(2007)06。1220-05 Crystal Growth and Qualitative Properties Evaluation of Cdo．8 MnoTe ． 2 YANG Bo，JIE Wan-qi，ZHANG Ji-jun，BAIXu-x“ (School of Material Science and Engineering，Northwestern Polytechnical University，Xi n 710072，China) (Received 11 January 2007．a~ce-pted 27 May 2007) Abstract：Cdo 8 Mno． 2Te crystal ingot with size of+30 mm×1 20 mm was successfully produced with vertical Bridgman method．The crystalline structure was verified by X—ray diffraction to be a pure cubic zinc blende structure．Double—crystal rocking curve measurement showed the FWHM to be 47．2arcsec， indicating a high crystalline perfection．Chemical etching was applied to reveal the crystal defects，such dislocations，Te inclusions and twins．Adopting an optical microscope，scanning electron microscopy with energy dispersive spectroscopy(SEM／EDS)，the morphology and distribution of these defects were analyzed．The results showed that the dislocation density was between 10 一10 cm～．Twins was observe