中间相炭材料包覆天然石墨球.pdfVIP

濠技 中间相炭材料包覆天然石墨球 周友元，李新海，郭华军，王志兴，杨 勇 (中南大学冶金科学与T程学院，湖南长沙410083) 摘要：以煤焦油为原料在天然石墨球表面包覆一层中间相炭材料制备出一种复合炭材料。研究了天然石墨球加入量对 复合炭材料电化学性能的影响。结果表明：随着天然石墨球添加量的减小，复合炭材料的充放电容量增加，首次充放电 效率减小。在200 mL煤焦油中加入7O g天然石墨时所制备的复合炭材料经700℃热处理2 h后性能最佳，可逆比容 量达378 mAh／g，充放电效率为91．3％。复合炭材料的循环性能得到了充分改善，3O个周期容量保持率97．04％。 关键词：锂离子蓄电池；复合炭材料；天然石墨球；充放电性能 中图分类号：TM 912．9 文献标识码：A 文章编号：1002—087 X(2007112—0963—03 Natural graphite coated by mesocarbon ZHOU You—yuan，L1 Xinmai，GUO Hua-jun，WANG Zhi—xing，YANG Yong (College ofMctallurgical Science and Engineering，Central South University,Changsha Hunan 410083，China) Abstract：Natural graphite coated by mesocarbon was prepared by depositing mesocarbon frOm the coal tar pitch on the surface of natural graphite．The effects of the weight of natu ral graphite on the electrochemical properties of carbon composite for lhe anode of¨lhium ion cells were studied The results show lhal lhe charge—discharge capacity of carbon composite increases and the initial coulombic efficiency reduces with the decrease of weight of natu ral graphite The sample of appending 70 g natural graphite to the coal tar pitch of 200 mL and heat——treated at 700 oC for 2 h has lhe besl electrochemical performances with a reversible capacity of 378 mAh／g and an initial coulombic efficiency of 91．3％ The cycling stability of the Li／C cells with carbon composite as anodes is improved its capacity retention ratio at the 30th cycle is 97．04％ Key words：Jjlhjum ion battery；carbon composite；natural graphite；charge-discharge properties 自从20世纪60年代发 存沥青液相炭化过程中存存炭 煤气厂)及球形天然石墨(山东某石墨厂)为原料 将200 mL 质中间相球体后，人们对中问相炭做球进行了大量的研究 ]： 的煤焦油置于0．5 L高压釜中，然后加入不同质量的球形天 叶l问相炭微球凶其具有独特的球状结构、比表面积低、堆积密