糖类对正渗透膜的膜污染研究 田禹1,2 李志能1 李俐频1 （1 哈尔滨 .doc

糖类对正渗透膜的膜污染 田 禹1,2 李志能1 李俐频1 （1. 哈尔滨工业大学市政环境工程学院，哈尔滨 150090； 2. 哈尔滨工业大学城市水资源与水环境国家重点实验室，哈尔滨 150090） 摘要 正渗透膜（FO）是一种低能耗的膜处理工艺，而膜生物反应器（MBR）是一种高效的污水处理工艺，其最大的瓶颈就是严重的膜污染问题，将FO应用到MBR中，即正渗透膜生物反应器。根据传统膜生物反应器的膜污染特点，研究SMP和EPS的主要组成成分中的糖类物质对膜的污染情况，利用海藻酸钠模拟糖类物质，并根据生活污水的特点，在海藻酸钠中加入钙、镁离子，研究其在含有不同金属离子时膜不同放置方式时的膜污染情况，将运行后的污染膜片剪下做SEM、AFM、FTIR-ATR分析。研究表明，海藻酸钠加不同金属离子的膜污染情况不一致，其膜污染大小顺序为藻酸钠+钙藻酸钠+钙+镁藻酸钠+镁 关键词：正渗透膜 糖类 膜污染 中图分类号 文献标识码 文章编号 Research on fouling propensity of carbohydrate for forward osmosis Tian Yu 1,2 Li Zhineng 1 Li Lipin 1 (1. School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China; 2. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China) Abstract Forward osmosis (FO) is a kind of low energy consumption technology, and membrane bioreactor (MBR) is an effective process for waste water treatment. However, the membrane fouling is a major obstacle to the wide application of MBRs. the FO combined with MBR in a system ,a new technology appeared 梠smosis membrane bioreactor (OMBR) . Based on the 要characteristic of conventional MBR and OMBR membrane fouling ,analysis the fouling property of carbohydrate ,which is the major composition of soluble microbial products (SMP) and extracellular polymeric substances(EPS). Alginate was used to simulate carbohydrate ,and based on the composition of waste water ,mixed calcium、magnesium ion in the alginate solution ,at the same time ,as the membrane is asymmetrical, analysis the fouling attendance of different membrane orientation . After the experiment , SEM、AFM、FTIR-ATR text was carried out to analysis the different fouling membrane . The result indicated that the membrane fouling propensity is alginate+Ca2+alginate+Mg2+ + Ca2+alginate+ Mg2+ and different membrane orientation showed different fouling property ,the active layer faced the feed tank presented a more serious membrane fouling . Key words: forward osmosis