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原子荧光必须了解的一些概念(Atomic fluorescence must understand some of the concepts)
原子荧光必须了解的一些概念(Atomic fluorescence must understand some of the concepts)
The first part of atomic fluorescence must have some key points
1. Advantages of atomic fluorescence: simple line spectrum; High sensitivity, low detection limit; This applies to multi-element analysis.
2. The relationship between the analyte fluorescence intensity and concentration, low concentration of atomic fluorescence analysis, fluorescence intensity with a simple linear relationship between measured concentration, concentration increased, due to the spectral lines broadening effect, imbibition, scattering effects, such as bending work curve appeared.
3. The intensity of atomic fluorescence and the intensity of excitation light can only be applied within a certain range of excitation light intensity. It is impossible to improve the detection limit by increasing the radiation intensity of the light source without limit.
4. Ways to overcome liquid phase and gas phase interference: increase pH, and increase the solubility of metal particles; To reduce the concentration of potassium borohydride; Increasing anti-interference reagents.
Atomic fluorescence photometer components: hydride generator, excitation light source, optical system, atomization system and photometric system.
6. Correction of light source drift and fluctuation: after a certain number of samples, the blank will be retested to fit the standard curve.
7. Several concepts
AFS: atomic fluorescence spectrometry. Atomic vapor absorb certain wavelengths of radiation energy and be excited, excited atom to emit a certain wavelength in the process of excitation radiation called atomic fluorescence detection according to the analysis of the atomic fluorescence analysis method into atomic fluorescence spectrometry.
Load flow: the main function is to react with reducing agent to generate initial ecological hydrogen (H?).
Reducing agent: the primary source of primary ecological hydrogen (H?).
Atomizer: the atomic location of the hydride ato
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