含碳酸盐水溶液中扑热息痛的光解研究.pdfVIP

第29卷第3期 Vo1．29。No．3 2008年3月 环 境 科 学 Mar．，2008 ENVIR0NMENTAL SCIENCE 含碳酸盐水溶液中扑热息痛的光解研究 高颖，杨曦 ，刘钰 (南京大学环境学院 污染控制与资源化研究国家重点实验室，南京 210093) 摘要：采用动力学方法研究了环境浓度范围内的扑热息痛在含碳酸盐溶液中的光解，比较了碳酸盐自由基和羟基自由基对扑 热息痛的光解效果，探讨了pH值、硝酸根离子、腐殖质、氯化钠、钙镁离子等因素对扑热息痛光解的影响．利用GC／MS技术鉴 定了扑热息痛的光解产物，并探讨了扑热息痛在碳酸根体系中可能的光解途径．结果表明，扑热息痛与碳酸盐自由基反应的 二级反应速率常数为k =5．0×10 L·(mol-S)～，低于与羟基自由基反应的二级反应速率常数 k =8．1×109L·(mol·s)一，但是 由于天然水体中碳酸盐自由基的稳态浓度较高，所以碳酸盐自由基对扑热息痛光解的影响和羟基自由基大致相当．提高体系 pH值，加入硝酸根离子、氯化钠或者钙镁离子都会加快扑热息痛的光解速率；而加入Suwannee河富里酸则会降低光解速率． 关键词：扑热息痛；碳酸盐；光解；自由基 中图分类号：X52 文献标识码：A 文章编号：0250—3301(2008)03．0643．07 Photodegradation of Paracetamol in Carbonate Solution GA0 Ying．YANG Xi．LIU YU (State Key Laboratory of Pollution Control and Resoume Reuse，School of the Environment，Nanjing University，Nanjing 210093，China) Abstract：The photodegradation of paracetamol in the solution of carbonate with comparably environmental concentration was studied through kinetics method．Experiments were carried out to compare the different photodegradation effects of paracetamol in the solution of carbonate radical and hydroxyl radica1．The effects of such factors，pH，nitrate，humic matters，chloride sodium，calcium and magnesium were also analyzed．The products of the photodegradation were identified with GC／MS，and the degradation mechanism of paracetamol was discussed． The results indicate that，the scondary reaction rate constant(k )between paracetamol and carbonate radical is 5．0×10 L·(mo卜s)一，which is lower than that with hydroxyl radical[k h=8．1×10 L。(mol。S) ]．But in natural aqueous system，【he stable concentration of carbonate radical is much higher than that of hydroxy1．Therefore，the effect of carbonate radical on paracetamol approximately equals to that of hydroxyl radica1．The