纳米氧化锌的机械力化学表面改性.pdfVIP

第19卷第2期 化 学 研 究 Vo1．19 No．2 2008年6月 CHEMICAL RESEARCH Jun．2008 纳米氧化锌的机械力化学表面改性 苏小莉，曹 智，李庆华，张治军 (河南大学特种功能材料教育部重点实验室，河南开封475004) 摘 要：采用机械力化学表面改性工艺，以硬脂酸为改性剂，在气流粉碎机中对纳米氧化锌进行解团聚和表面改 性，并借助SEM、XRD、兀．一IR和XPS对改性前后的氧化锌粉体进行结构表征．结果表明：硬脂酸分子化学键合在 氧化锌表面．改性前后氧化锌的晶体结构相同，其颗粒的团聚性降低，二次粒径明显减小．通过测定改性样品的 活化指数和亲油化度，选择最佳的改性剂用量为氧化锌质量的10％，氧化锌表面亲油疏水，在有机溶剂中有较 好的分散性． 关键词：纳米氧化锌；表面改性；硬脂酸 中图分类号：TQ 016．1 文献标识码：A 文章编号：1008—1011(2008)02—0074—04 Mechanochemical Modification of ZnO Nanoparticles SU Xiao．1i，CAO Zhi，LI Qing—hua，ZHANG Zhi-jun f Key Laboratoryfor Special Functional Materials ofMinistry of Education，Henan University，Kaifeng 475004，Henan，China) Abstract：Industrial zinc oxide nanoparticles were modifed with stearic acid by mechanochemical mod— ification in jet mill by batch operation for the purpose of reducing the aggregation of ZnO nanoparticles． ZnO nanoparticles were characterized by SEM，XRD，FT—IR and XPS．A covalent bond was formed by chemical reaction between the hydroxyl groups on the surface of ZnO nanoparticle and carboxyl groups f CO0—1 of stearic acid．The modification did not alter the crystalline structure of ZnO nanoparticles． In addition，the aggregation of ZnO nanoparticles was greatly reduced and the twice particles size be· came smaller．The activation index and lipophilic degree of modified ZnO nanoparticles were measured and the optimal amount of stearic acid was 1 0％ weight of ZnO raw materials．ZnO nanoparticles had much better dispersibility in organic solvents after modification due to the lipophilic and hydrophobic groups on the surface of ZnO nanoparticles． Keywords：ZnO nanoparticles；surface modif