2008配合物试题A.docVIP

苏州大学配位化学(双语)课程试卷A 共页 院系 年级 专业 学号 姓名 成绩 一、选择题(18×2) 1. Indicate the coordination number and the oxidation number of the transition metal in the following complex: [Co(C2O4)3]3- ? A．?4, 3+ B.? 4, 4+ C.? 6, 6+ D.? 6, 3+ 2. What are the geometries of the following two complexes? (i) [Fe(C2O4)3]2- ; (ii) [Zn(NH3)4]2+ A.? tetrahedral, octahedral B.? octahedral, octahedral C.? tetrahedral, tetrahedral D.? octahedral, tetrahedral 3. What is the respective central-metal oxidation state, coordination number, and the overall charge on the complex ion in K[Cr(NH3)2(NCS)4]? A.? +3, 6, +1 B.? +3, 6, -1 C.? -3, 4, -1 D.? -3, 2, -1 4. What is the charge on the complex ion in Al2[CuCl4]3? A.? +3 B.? -3 C.? +2 D.? -2 5. What is the coordination number of copper in the [Cu(en)2(gly)]2+ ? A.? 2 B.? 4 C.? 6 D.? none of these 6. What is the coordination number and oxidation state of the central atom in [Co( bipy)2(NH3)2]3+? A.? 4, 3+ B.? 5, 2+ C.? 6, 3+ D.? 6, 2+ 7. Which of the following is the correct formula for the oxotetrathiocyanovanadate(IV) ion: A.? [VOSCN]+ B.? [VO(SCN)4]2- C.? [VO(SCN)4]- D.? [VO(SCN)4] 8. How many bonds can ethylenediaminetatraacetato form to a metal ion? A.? 3 B.? 5 C.? 4 D.? 6 9. Name the following compound: K2[Cr(CN)5CO]. A.? dipotassium chromium cyanidocarbonyl B.? potassium carbonylpentacyanochromium(III) C.? potassium carbonylpentacyanochromate(III) D.? dipotassium carbonatopentacyanochromate(III) 10．Give the number of d electrons associated with the valence electrons of the central metal ion in the following complex: [Mo(EDTA)](ClO4)2 A.? 0 B.? 1 C.? 2 D.? 11. What is the number of unpaired electrons for the Fe3+ ion in a high-spin octahedral