真丝织物无甲醛固色剂M09的合成与应用.PDFVIP

Vol.48 第48卷 No.10, Oct. 2011 2011年10月 第10期 研究与技术 真丝织物无甲醛固色剂M09的合成与应用 许 磊1，2, 张 蓉3，4 (.苏州经贸职业技术学院 轻纺系，江苏 苏州 25009；2.江苏省丝绸工艺与材料工程技术研究开发中心，江苏 苏州 25009； 3.苏州市纤维检验所，江苏 苏州 2528；4.国家丝绸及服装产品质量监督检验中心，江苏 苏州 2528) 摘要：在固色剂分子上引入反应性基团，使之在真丝织物表面既能自交联，又能与染料、蚕丝起架桥作用；并在分子中引入羟基、氨 基等基团，利用固色剂与纤维间的分子引力增加固色剂的固着强度。以乙烯胺、丙烯酸等为原料合成一种无甲醛固色剂M09，应用于 处理真丝织物，效果良好。对酸性染料染真丝后的固色效果进行了测试，摩擦牢度、皂洗牢度、汗渍牢度均有提高。该固色剂使用方 便，在生产过程和染色应用过程中都达到了无甲醛的要求，是一种环保型固色剂。 关键词：酸性染料；无甲醛；固色剂；合成 中图分类号：TS95.2 文献标志码：A 文章编号：00-7003(20)0-00-03 Synthesis and application of formaldehyde-free fixing agent M09 for silk fabric dyeing XU Lei1,2, ZHANG Rong3,4 (1. Department of Light and Textile Industry, Suzhou Institute of Trade Commerce, Suzhou 215009, China; 2. Jiangsu Silk Technology and Materials Engineering Research and Development Center, Suzhou 215009, China; 3.Suzhou Institute of Inspection on Fiber, Suzhou 215128, China; 4.National Silk and Garment Quality Supervision Testing Center, Suzhou 215128, China) Abstract: In the introduction of reactive groups, fixing agent molecules can form self-crosslinking on the surface of silk fabric, and can from the bridging with dyes and silk. At the same time, introduction of hydroxyl group or amino group in the molecule, can increase fixation strength of fixing agent with the molecular attraction between fixing agent and the fibers. A non-formaldehyde fixing agent named M09 was synthesized with ethylene amines and acrylic acid. It has good effect to treat silk fabrics with this fixing agent. The fixing effect of silks was tested after dyeing by the acid dyes. The results showed that rubbing fa