微波辐射作用下氰乙基化木材的制备.PDF

40 1 V o.l 40 N o. 1 2006 1 B iom ass Chem ical Eng ineer ing Jan. 2006 微波辐射作用下氰乙基化木材的制备 万东北, 尹 波, 罗序中 (赣南师范学院化学与生命科学系, 江西 赣州 341000 : 利用微波辐射对杉木 行氰乙基化改性, 研究了各种反应条件对氰乙基化反应的影响并用红外光谱对氰乙基 化木材 行了初步表征结果表明, 2 g杉木粉用 K SCN 饱和低浓度 N aOH 浸渍 60 m in, 丙烯腈 17 mL, 温度在 40 ~ 50 下, 微波辐射 20 ~ 60 m in, ( 实际反应时间为 80 ~ 120 m in , 辐射功率用 650W 的 30 % , 可获得与传统的恒温水浴反应 240m in 同样增重 50% ~ 60% 的氰乙基化木材, 但前者可缩短 50 % 的反应时间 : 木材; 氰乙基化; 化学改性; 微波辐射 : 0532. 23; TQ 351 : A Preparation ofM odifiedW ood by Cyanoethylation underM icrow ave Radiation WAN Dong-be,i Y IN Bo, LUO Xu-zhong ( D epartm ent o f Chem istry and life Science G annan T eachers Co llege, G anzhou 341000, China A bstrac t: China fir w as m od if ied by cyanoethylation under m icrow ave radiation. T he cyanoethy lated w ood w as charac terized by IR. The sam e w e ight ga in ( 50 % - 60 % could be obta ined as that o f conventiona lm ethod, but the reaction tmi e w as shortened from the prmi ary 240 m in to 120m in. T he reaction conditions are as fo llow s: 2 g o f China fir is soaked in saturated and low concentrated N aOH so lution for 60 m in, cyanoethy lene 17 mL, tem pera ture 40 - 50 , rad ia tion tmi e 20 - 60 m in ( the actua l reaction tmi e 80 - 120m in and 30 % o f 650 W m icrow ave pow er. K ey w ord s: w ood; cyanoe thy la tion; chem ical mod if ication; m icrow ave radiation , 1 , 1. 1 , ( 80 , 10% ; K SCN , N aOH; [ 1~ 9] [ 3~ 6] , W P650; FT- IR 360 H on[ 7]