种煤沥青炭微观结构及其性能的对比研究-中南大学学报.PDF

第 39 卷第 5 期 中南大学学报自然科学版( ) Vol.39 No.5 2008 年 10 月 J. Cent. South Univ. (Science and Technology) Oct. 2008 3 种煤沥青炭微观结构及其性能的对比研究 张红波，沈益顺，左劲旅，熊 翔，尹 健 ( 中南大学 粉末冶金国家重点实验室，湖南 长沙，410083) 摘 要：将高温煤沥青、中温煤沥青、浸渍剂沥青在常压下炭化，经 2 300 ℃石墨化处理，制备 3 种煤沥青炭。 利用扫描电子显微镜(SEM)观察煤沥青炭的显微结构；采用X射线衍射法(XRD)检测煤沥青炭的石墨化度；通过氮 吸附法测定煤沥青炭的比表面积(SBET) ；采用热重(TG/DTG)分析手段测试并分析煤沥青炭的氧化性能。研究结果 表明：煤沥青的族组分影响煤沥青炭的形貌，喹啉不溶物含量低有利于流线型结构的形成；高温煤沥青炭微观结 构主要以流线型和镶嵌型为主，中温煤沥青炭和浸渍剂沥青炭以流线型为主，但浸渍剂沥青炭流线型结构取向性 好；煤沥青炭中含有流线型结构越多，则其石墨化度越高，比表面积越低；煤沥青炭的氧化失重主要发生在 700~900 ℃，浸渍剂沥青炭的抗氧化性能最好。 关键词：煤沥青炭；微观结构；氧化性能；石墨化度；比表面积 中图分类号：V258.3 文献标识码：A 文章编号：1672−7207(2008)05−0956−06 Contrast studies on microstructure and properties of three kinds of coal-tar pitch derived carbon ZHANG Hong-bo, SHEN Yi-shun, ZUO Jing-lü, XIONG Xiang, YIN Jian (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Using high temperature pitch, medium temperature pitch and impregnating pitch, three kinds of coal-tar pitch carbon were prepared by carbonization at atmospheric pressure and graphitization at 2 300 ℃ successively. Their microstructures, graphitization degree and specific surface area (SBET) were investigated by scanning electric microscopy (SEM), X-ray diffraction (XRD) and nitrogen adsorption respectively. Finally, the oxidation properties of the three kinds of carbon were tested by thermogravimetric. The results show that the component of coal-tar pitch affects the microstructure of coal-tar pitch carbon. Lower content