超声浸渍法制备高温煤气脱硫剂及其表征和活性研究.PDF

第 29 卷 第 35 期 中 国 电 机 工 程 学 报 Vol.29 No.35 Dec. 15, 2009 2009 年 12 月 15 日 Proceedings of the CSEE ©2009 Chin.Soc.for Elec.Eng. 83 文章编号：0258-8013 (2009) 35-0083-06 中图分类号：TK 224 文献标志码：A 学科分类号：480·10 超声浸渍法制备高温煤气脱硫剂 及其表征和活性研究 孙剑峰，刘建忠，王洁，周俊虎，胡亚轩，岑可法 (能源清洁利用国家重点实验室(浙江大学) ，浙江省 杭州市 310027) Preparation of Sorbents for Hot-gas Desulfurization by Ultrasonic Impregnation and Its Characterization and Desulfurization Activity SUN Jian-feng, LIU Jian-Zhong, WANG Jie, ZHOU Jun-hu, HU Ya-xuan, CEN Ke-fa (State Key Laboratory of Clean Energy Utilization(Zhejiang University), Hangzhou 310027, Zhejiang Province, China) ABSTRACT: Six hot-gas desulfurization metal sorbents 有大幅度的提高，特别是铁系脱硫剂。几种物系脱硫剂在相 including Fe, Mn, Cu, Ce, Ca and Zn were prepared by an 同超声条件下制备得到的脱硫剂的活性比较结果为：Fe ultrasound-assisted impregnation method and by a classical MnCuCeCaZn 。 impregnation method. The desulfurization activity of the high 关键词：超声浸渍；高温；脱硫剂；煤气化；硫化氢 temperature desulfurization sorbents was studied in a fixed-bed reactor. The physical and chemical properties of the sorbents 0 引言 were analyzed by means of inductively coupled plasma 我国一次能源消费中煤的比重高达 70%，其中 atomic emission spectrometry(ICP-AES), Scanning Electron 大部分用于发电，而煤燃烧后不可避免地产生了各 Microscope (SEM), and X-ray diffraction (XRD). The results 种污染物；如何高效清洁发电成为目前能源领域的 showed that the use of ultrasond increased the content of active 重要课题之一。IGCC 是目前最有发展前景的洁净 ingredient in the sorbents, improved the pore structure, and 煤发电技术之一，但目前国内外的 IGCC 技术还没 thinned