钙指示剂分光光度法测定水中的钙.PDF

2001 年12 月 Dec.,2001 第21 卷第12 期　　　　　　　　　　Industrial Water Treatment 　　　　　　　　　　　Vol.21No.12 杨亚玲,毕莉,刘谋盛 (昆明理工大学生化学院,云南 昆明　650224) 　　[] (Kalces), , 。, pH 5.2-, 1∶1, 4 λ =620 nm, ε=1.33×10 L/(mol·cm), , 0～ 1.6 mg/ max L 。196, 96.5%～103%, 。 　　[] ;; 　　[] X832　[] B　[] 1005-829X(2001)12-0034-02 Spectrophotometric determination of calcium in water with Kalces YANG Ya-ling,BI Li,LI Mou-sheng (Biologica l and Chemical Engineering College,Kunming University of Technology ,Kunming 650224, China ) 2+ Abstract :The color reaction of Ca with Kalces,many factors of influenceon the sensitivity and stability and the optimi- um operational conditions have been studied.The experimental results reveal that in the presence of HAc-NaAc buffer 2+ 4 solution medium(pH 5.2),Ca can react withKalces to form a 1 ∶1blue complex.Themolar absorptivity is 1.33×10 L/(mol·cm)at 620 nm.nder thiswavelength and optimum operational conditions,when the concentration rangeof cal- cium content is 0～1.6 mg/L,Beers law is obeyed.On the basis of testing 10 kinds of common coexistent interfering 2+ ions, thismethod can be applied to the determination of Ca in 6 kinds of water samples.The recovery ratio is 95.6% to 103%.It is very satisfactory. Key words:Kalces;spectrophotometric;determination of calcium 　　 1　 ,, 1.1　主要仪器和试剂 , EDTA 　　V-2400 (); ; PHS-10B ();100 ; mg/L:2 h 120 ℃ , AR CaCO 0.249 7 g , 3 ,。 , 3 mol/L , , CO ,, 2 , ,,