Al_3_在C_S_H凝胶中的存在形态.pdf

Al3+ 在在 C-S-H 凝胶中的存在形态凝胶中的存在形态 在在 凝胶中的存在形态凝胶中的存在形态 封孝信，苗小磊，胡晨光 （河北理工大学材料学院，河北省无机非金属材料实验室，河北 唐山 063009 ） 摘要摘要：采用化学方法合成了含： Al3+ 的 C-S-H 凝胶，并采用核磁共振 （NMR ）测定了 Al3+在其中的配位数，分析了 Al3+ 摘要摘要：： 在 C-S-H 凝胶中存在形态。结果表明，Al3+可以进入 C-S-H 凝胶的结构中，当 Al3+较少时，以[AlO ] 四面体的形式占据 4 Si4+ 的位置。随Al3+数量的增大，占据 Si4+位置的数量增加。但Al3+取代 Si4+ 的程度是有限的，存在一最大值。当Al3+取 代 Si4+饱和后，剩余的Al3+ 以[AlO ]八面体的形式存在于 C-S-H 凝胶结构中的层间位置。 6 关键词关键词：：C-S-H 凝胶；Al3+配位数；存在形态 关键词关键词：： 3+ Investigation on Form of Al in C-S-H Gel FENG Xiaoxin , MIAO Xiaolei , HU Chenguang (Hebei Province Key Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering，Hebei Polytechnic University, Tangshan 063009, China) Abstract: C-S-H gel containing Al3+ was synthesized with chemical method, and the coordination number of Al3+ in the structure of the gel was tested with nuclear magnetic resonance (NMR). The results show that Al3+ can enter into the structure of C-S-H gel, and when the amount of Al3+ is small, Al3+ is in the form of [AlO ] tetrahedron, and occupies the site of bridging 4 [SiO ] tetrahedron in silicate chain. With A/S increasing, more Si4+ is substituted by Al3+. However, the amount of Si4+ which can 4 be substituted by Al3+ is limited, and it comes up to a maximum. With Al3+ continuing to increase, redundant Al3+ is in the form of [AlO ] octahedron, and exists in the inte