甲基磺酸对PBO纤维的表面改性.pdf

Vol. 22 No. 2 2009 6 Journal of Functional Polymer s 165 PBO 邱汉亮, 钱 军, 樊黎虹, 刘小云, 李欣欣, 韩哲文 ( 华东理工大学材料科学与工程学院, 特种功 高分子材料及相关技术教育部重点实验室, 上海2002 7) : 采用甲基磺酸( M SA) 溶液对PBO 纤维表面进行化学改性, 用单丝拨出试验测定了改性 前后PBO 纤维与环氧树脂基体的界面剪切强度, 并通过扫描电镜( SEM) X- 射线光电子 谱 ( XPS) 接触角分别对处理前后纤维的表面形貌表面组成以及表面自由 进行了表征研究结果 表明: 在甲基磺酸质量分数为60%的溶液中, 60 e 下处理6 h 的PBO 纤维与环氧树脂基体的界面 剪切强度比未处理的提高了81% , 并且纤维表面O 元素的质量分数增加了 1 . %, 表面自由 增 加了17. % 当溶液中甲基磺酸的质量分数处理时间和处理温度进一步提高时, PBO 纤维的皮 层将遭受破坏, 导致界面剪切强度下降 : PBO 纤维; 甲基磺酸; 界面剪切强度; 表面改性 : O6 6 : A : 1008-9 57( 2009) 02-0165-08 Surface Modification of PBO Fibers by Methanesulfonic Acid Q IU Han-liang, QIAN Jun, FAN Li-hong, LIU Xiao- yun, LI Xin-xin, HAN Zhe-w en ( Key Laboratory of Specially Functional Polymeric M aterials and Related Technology of the M inistry of Education, School of M aterials Science and Engineering, East China U niversity of Science and Technology, Shanghai 2002 7, China) Abstract: T he surface modification of PBO fiber by methanesulfonic acid ( MSA) w as studied. T he inter- facial shearing strength ( IFSS) of PBO fiber-epoxy resin w as measured by single fiber pull out test. The surface morphology, composition and surface free energy of PBO fiber before and after surface modification w ere investigated by scanning electron microscopy ( SEM) , X-ray photoelectron spectroscopy ( XPS) and contact angle measurment, respectively. T he results show ed that, compared w ith untreated PBO fiber, PBO fibers treated in 60% M SA at 60 e for 6 h had excellent surface properties. T he IFSS of treated PBO fiber-epoxy resin, the oxygen content, and surface free energy increased by 81%, 1 . % and