共沉淀流变相法制备LED荧光粉文献翻译.docxVIP

Photoluminescence enhancement of YAG:Ce3+phosphor prepared byco-precipitation-rheological phase method光致发光增强的YAG：Ce3 +的荧光粉制备——共沉淀流变相法作者：YE Xinyu , LONG Zhen 2, YANG Youming, NIE Huaping, GUO Yanwei, CAI YufaAbstract:YAG:Ce3+phosphor was prepared by a novel co-precipitation-rheological phase method. The resulting YAG:Ce3+phosphor wascharacterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescent emission spectra. By using acetic acidas solvent, YAG:Ce3+powder with small particle size （≤2 um） was obtained at a relatively lower sintering temperature of 1400 oC. With thecontent of acetic acid increasing, small particles dissolved and disappeared, but larger particles grew up and changed its shape from sphericalto partially rectangular. Meanwhile, the emission intensity of the sample prepared by co-precipitation-rheological phase method was about43% higher than that of the sample prepared by co-precipitation method. It was assumed that the significant improvement of luminescencewas mainly because the rheological phase presented a better diffusion environment, and therefore, a better homogeneity of activators of Ce3+.Keywords: phosphors; luminescence; YAG:Ce3+co-precipitation-rheological phase method; rare earths摘要：YAG：Ce3 +荧光粉是用一种新型的共沉淀流变相法制备的。由此制备出的YAG：Ce3 +的荧光粉，通过X射线衍射（XRD），扫描电子显微镜（SEM）和光致发光光谱仪对合成的荧光粉进行了表征。通过使用醋酸作为溶剂，YAG:Ce3+粉末粒径小（≤2微米），可获得相对较低的烧结温度，约1400 OC。随着醋酸浓度的增加，小颗粒粉末溶解和消失，但较大的颗粒会变大并且它的形状会从球形变成的矩形。同时，通过共沉淀流变相法制备的样品的发光强度比共沉淀方法制备的样品发光强度高出约43％。这里假设荧光粉发光显着改善，主要是因为流变阶段拥有一个更好的扩散环境，因此，更好地的使Ce3+激活为同质正离子。关键词：荧光粉发光; YAG：Ce3+共沉淀流变相法;稀土Compared with incandescent or fluorescent lamps, LEDbasedlight sources have many advantages such as superiorefficiency, long lifetime, high reliability and in particular,without mercury contamination. The combination of yellowphosphor YAG:Ce3+and blue LED is commonly used forwhite-light generation[1–4]. In this case, pure YAG phase isfavorable for luminescent properties of phosphors; however,the solid state re