脐橙总糖近红外光谱模型传递研究 - 食品科学.pdf

28 2012, Vol. 33, No. 03 食品科学 ※基础研究 胡润文，夏俊芳 * (华中农业大学工学院，湖北 武汉 430070) 为实现近红外光谱模型在同类光谱仪器间的共享，以脐橙总糖为例，在主仪器上建立最优的偏最小二乘 (PLS)近红外光谱模型，采用斜率截距(Slope/Bias)校正法和直接校正(DS)算法把主仪器上建立的模型传递到从仪器 上，并探讨标准化样品个数对模型传递效果的影响。研究表明：在主仪器建立的模型经 DS 算法传递后，从仪器 预测集的预测标准差(RMSEP)为0.448%，经Slope/Bias 校正法传递后的预测标准差(RMSEP)为0.756%，DS 算法更 优于 Slope/Bias 校正法，利用直接校正法实现脐橙总糖傅里叶近红外光谱模型传递是可行的。 脐橙；总糖；近红外；斜率截距法；直接校正法；模型传递 Transfer of NIRS Calibration Model for Determining Total Sugar Content in Navel Orange HU Run-wen ，XIA Jun-fang* (College of Engineering, Huazhong Agricultural University, Wuhan 430070, China) Abstract ：In order to achieve NIRS (near infrared reflectance spectroscopy) calibration model sharing among similar NIRS instruments, an optimal NIRS partial least square (PLS) regression model was established using the major instrument and transfer to the minor instrument by either slope bias correction (SBC) or direct standardization (DS). In addition, the dependence of calibration transfer on the number of standardization samples was explored. The results showed that the root mean squared errors of prediction (RMSEP) for the calibration model were 0.448% and 0.756% after standardization by DS and SBC, respectively. Thus, the DS method was better than the SBC method and could be used to successfully transfer the calibration model Key words ：navel orange ；total sugar ；near infrared ；slope/bias correction ；direct standardization ；calibration transfer 中图分类号：O657.33 文献标识码：A 文章编号：1002-6630(2012)03-0028-05