超细铋金属粉体的制备 - 湖南工学院.pdf

∀ 164 ∀ 2006 5 20 # * 1, 2 2 2 胡汉祥 , 谢华林 , 何晓梅 ( 1 , 4 10083; 2 , 42 1008) 铋的蒸气压小, 熔点低, 用直接蒸发冷凝的方法制备铋粉体较 难采用先将铋蒸发氧化制备氧化铋纳 米粉体, 然后在低于铋的熔点下, 用氢气还原的方法制备了超细铋粉体XRD 与 SEM 分析结果表明: 氧化铋为 Bi O , 平均粒径为37nm; 用氢气还原所得粉体为纯铋, 平均粒径为222. 1nm 2 3 Preparati on of Superfine Bismuth Powders 1, 2 2 2 H U H anxiang , XIE Hualin , H E Xia mei ( 1 Sch l f Chemist ry and Chemical Engineering, Central S uth University , Changsha 4 10083; 2 Department f Chemistry and Chemical Engineering, Hunan Building Materials C llege, Hengyang 42 1008) Abstract T he superfine bismuth p wders have been prepared by reducing bismuth x ide ( that is t xidize the bismush at vap rphase w ith adding agent at bel w 1140 ) with hy dr gen at bel w melt ing p int f bismuth. The p wders are analyzed by XRD and SEM . The results sh w that bismuth x ide p w der is Bi O , and the average size 2 3 is less than 37nm. And the p wder prepared by reducing the bismuth x ide p wder w ith hy dr gen is pure rh mb hed ral bismuth, and the average size is ab ut 222. 1nm. T he charact eristics f preparing pr cess is als discussed in this paper. Key words bismuth x ide, bismuth, x idati n and reducti n, nan meter p wders 0 , , , Bi ( [ Xe] , 14 10 2 3 4f 5d 6s 6p ) , , , 1 2 , 10 , ,