钛铁矿机械活化强化浸出的研究 - 钢铁钒钛.pdf

26 2 Vol. 26,No. 2 2005 6 IRON STEEL VANADIUM TITANIUM June 2005 张雪轻, 李 春, 梁 斌 ( , , 610065) : ( 70B1) , XRD , , h , , 55.7 kJ/ mol 23. 7 kJ/ mol 30% ~ 50% , , , : ; ; :TQ630. 6 :A : 100 - 7638(2005) 02- 0011- 05 Study on Enhanced Leaching of Mechanically Activated Ilmenite Zhang Xueqing, Li Chun, Liang Bin ( Key Laboratory of Multi- phaseMassTransfer and Chemical Reaction Engineering, College of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China) Abstract :Mechanical activation of rock- type Panzhihua ilmenite was investigatedwith a tumbling ball mill at 70B1 ratio of ballBore mass. XRD analysis demonstrated the crystallite size of ilmenite decreased with the in- creasing of milling time, and remained practically unchanged beyond h of milling. The dissolution kinetic ex- periments at various temperatures showed the apparent activation energy of the ore reduced from 55. 7 kJ/mol in initial leaching stage to 23. 7 kJ/ mol with the extending of milling time. It was found that the apparent Ar- rhenius energy is closely related to the crystallite size. The digestion of activated ilmenite at a sulfuric acid of 30% ~ 50% concentration was also studied. With increasing of the activation time, the effect of acid concen- tration on leaching dropped, this indicates that the dissolution of ilmenite under low acid concentration and low leaching temperature is feasible. Key words: ilmenite; mechanical activation; leaching 用中和排放的方法, 既增加了中和成本, 又带来二次 0 引言