聚合松香HEMA酯化物与苯乙烯的共聚研究.pdfVIP

聚合松香HEMA 酯化物与苯乙烯的共聚研究1 武安福，余彩莉，张发爱* 桂林理工大学材料科学与工程学院，桂林541004 摘要：以聚合松香（PR ）与甲基丙烯酸-β-羟乙酯（HEMA ）的酯化物（PRH ）为单体，采用自由基 聚合制备了与苯乙烯（St ）的共聚物（PRHS ）。探讨了单体比例、反应温度、引发剂用量和反应时间对共 聚反应的影响。用红外光谱（FTIR ）、热重分析（TGA ）和差示扫描量热分析（DSC ）对产物的结构、热 稳定性和玻璃化转变温度进行了测试表征。结果表明：成功合成了聚合松香HEMA 的酯化物与 St 的共聚 物；共聚物的热稳定性高于酯化物，苯乙烯用量越多，共聚物热稳定性和玻璃化转变温度越高；PRH 与St 共聚较佳的反应条件为：PRH 与St 质量比为1:1，反应温度为110℃，引发剂用量为单体的1 wt%，反应时 间为8 h ，在此条件下，共聚产率达到86.7%。 关键词：聚合松香；甲基丙烯酸-β-羟乙酯；酯化物；共聚 Study on Copolymerization of Polymerized Rosin and 2-Hydroxyethyl Methacrylate-Based Ester and Styrene Wu Anfu, Yu Caili, Zhang Faai* College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004 Abstract: A copolymer (PRHS) was prepared from polymerized rosin (PR) and 2-hydroxyethyl methacrylate (HEMA) based ester (PRH) and styrene (St) via free radical solution copolymerization . The effects of monomer ratio, reactive temperature, initiator level and reaction time on copolymerization were studied. The molecular structures, thermal stabilities, and the glass transition temperatures (Tg) of products were characterized by Infrared Spectroscopy (FTIR), thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results showed that PRHS was prepared successfully. The thermal stability of the copolymer was better than the ester. With the increase of St level, the thermal stability and Tg of copolymer improved. When the weight ratio of the PRH and St was 1:1, the initiator amount was 1 wt%, it produced the highest yield (86.7%) after polymerization at o 110 C for 8 h. Key words ：Polymerized rosin, 2-Hydroxyethyl methacrylate, Ester, Copolymerization 松香是把松树分泌出来的粘液蒸馏除去溶剂和松节油后而得到的一种透明、脆性的天然 可再生树脂，而聚合松香 （PR ）是枞酸型树脂酸在催化剂的作用下异构形成的，与松香相 比，PR 具有软化点高、色泽浅、不结晶、抗氧化等特性[1]。PR 以二聚体为主，软化点在 110~ 150℃