T309-二氧化钛纳米管稳定Pickeri_省略_备PS_TiO_2纳米管复合微球_张方.pdf

65 4 Vol.65 No.3 April 2014 2014 4 CIESC Journal 1526 Pickering PS/TiO2 ( 230009) -KH-570TiO2 Pickering /TiO2 IR HRTEM(FESEM)X XPS TiO2 TiO2 mKH-570/mTiO2 =15% TiO2 Pickering TiO2 TiO2 Pickering DOI 10.3969/j.issn.0438-1157.2014.04.050 O 631 A 04381157201404152605 Polystyrene /TiO nanotubes composite microspheres fabricated via Pickering 2 emulsion polymerization stabilized by TiO2 nanotubes ZHANG FangSHI TiejunZHOU XunZHOU Hai’ouWU Jing (School of Chemical Engineering, Hefei University of Technology, Hefei 230009, Anhui, China) Abstract: TiO2 nanotube prepared via the hydrothermal method was modified with KH-570 and then the modified TiO2 nanotube was used as an emulsifier to fabricate PS/TiO2 nanotube composite microspheres via Pickering emulsion polymerization. The TiO2 nanotubes and composite microspheres were characterized by IR, optical microscope, HRTEM, FESEM and XPS. The surface wettability of TiO2 was measured with contact angle meter. When the value of m /m was 0.15, the modified TiO nanotube possessed the best surface wettability and KH-570 TiO2 2 it could satisfactorily stabilize the St-in-water Pickering emulsion polymerization. And then the composite microspheres with PS nucleus and dense, homogeneous TiO2 nanotubes shells could be obtained via Pickering emulsion polymerization. Key words TiO2 nanotubes; hydrothermal; Pickering emulsion;