锡铜包覆涤纶织物的结构与性能研究.PDFVIP

Vol.48 第48卷 No.11, Nov. 2011 2011年11月 第11期 研究与技术 锡铜包覆涤纶织物的结构与性能研究 吴熊平，马春霞，李 楠，吕汪洋，姚玉元，陈文兴 (浙江理工大学 先进纺织材料与制备技术教育部重点实验室，杭州 3008) 摘要：在涤纶织物镀铜的基础上电镀锡制得了锡铜包覆涤纶织物，通过扫描电镜和电子能谱对其进行表征，研究了电压和时间对表 面电阻的影响，并测试了结合牢度、抗氧化性和电磁屏蔽性能。结果表明，当电镀电压为 V、时间6 min时，镀铜涤纶织物表面包 覆了一层厚度约为3.0 µm的锡，且锡铜包覆涤纶织物的表面电阻随电压的增加而减小，随时间的增加先减小后基本保持不变。金属 锡铜镀层与涤纶织物之间的结合牢度良好，其摩擦牢度可达4～5级。该锡铜包覆涤纶织物对频率2 000～3 000 MHz电磁波的屏蔽可 达99.999 99 %，因此所制备的锡铜包覆涤纶织物不仅具有良好的电磁屏蔽性能，而且通过电镀锡实现镀铜层防氧化的目的，有效地 增强了化学镀铜涤纶织物的实用性。 关键词：电镀锡；化学镀铜；涤纶织物；结构；性能 中图分类号：TS95.6；TQ53 文献标志码：A 文章编号：00-7003(20)-000-04 Study on the structures and properties of tin-copper-coated PET fabrics WU Xiong-ping, MA Chun-xia, LI Nan, LV Wang-yang, YAO Yu-yuan, CHEN Wen-xing (Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China) Abstract: Tin electroplating was proceeded on electroless copper plated PET fabrics to obtain tin-copper coated PET fabrics. The fabrics were characterized by SEM and EDS. Effects of voltage and time for surface resistance were investigated. Adherence stability, anti-oxidation property and electromagnetic shielding performance were tested. The results demonstrated that a uniform tin layer was plated on the surface of copper plated PET fabrics with about 3.0 µm thickness, when set the voltage of 1 V and the time of 6 min as the process of tin electroplating. The surface resistance was decreased with the increasing of voltage and time, and it was almost keep the line with the time continue increasing. The tin-copper layer and fabric had good adherence stability, and the rubbing fastness was