正溴丁烷 的制备 思考题（Preparation of n-bromobutane）.docVIP

正溴丁烷 的制备 思考题（Preparation of n-bromobutane） tetrabromobutane 1. What is the role of sulfuric acid in this experiment? The amount of sulfuric acid and the concentration is too large or too small what is not good? Answer: action is: reactant, catalyst. When too large, the reaction generates a large amount of HBr running out, and easy to oxidize bromine ion to bromine; After an hour, the reaction is incomplete. 2. What impurities may be in the products after the reaction? What is the purpose of each step washing? Why do I need to use a dry separatory funnel when washing with concentrated sulfuric acid? A: it may contain impurities: n-c4h9oh, (n-c2h5), HBr Each step of washing purposes: (1) water in addition to the six HBr, most of the n - C4H9OH (2) sulfuric acid wash (n - C4H9) 2 o, the rest of the n - C4H9OH (3) for most - H2SO4 (4) use NaHCO3 wash with water in addition to the rest of the - H2SO4 (5) finally washed with water except NaHSO4 residues, such as excessive NaHCO3. With concentrated sulfuric acid washing, the purpose of using the dry separatory funnel is to prevent the concentration of sulfuric acid and influence the washing effect. If 1 - bromobutane containing n-butyl alcohol distillation will form before fractions (1 - bromobutane - n-butyl alcohol constant boiling point 98.6 ℃, inclusive of our 13% n-butyl alcohol), and results in the decrease of refined production rate. 3. The product is washed with a liquid funnel. The product is sometimes in the upper and lower layers. What is the easiest way to judge? Answer: pour a little bit of superfluid from the split funnel or release a little bit of the lower level liquid in a water test tube to see if there is any oil bead appearing to judge. 4. Why do you need to wash with water before washing with saturated sodium bicarbonate solution? Answer: first washed with water, can remove part of sulfuric acid, to prevent wash with sodium bicarbonate, sodium bicarbonate and sulfuric acid reaction to generate a large