太阳光Fenton氧化对含酚废水生物降解影响研究.pdfVIP

第31卷 第7期 l‘诧．辩 砝 Vo1．31 No．7 2008年7月 Environmental ScienceTechnology Ju1． 2008 太阳光Fenton氧化对含酚废水生物降解影响研究 刘琼玉， 刘立， 崔菲菲 (江汉大学化学与环境工程学院，湖北 武汉 430056) 摘 要：研究了太阳光Fenton氧化预处理对含酚废水生物降解性的影响及太阳光Fenton氧化一生化法联合工艺对煤气含酚废水的 处理效果。结果表明，煤气含酚废水和模拟含酚废水的生物降解性均较差，太阳光Fenton氧化预处理可明显提高含酚废水的生物降解 性，随着H202投加量的增加，废水的BOD ／COD比值逐渐增大，生物降解性明显增强。煤气含酚废水直接进行生化处理的COD和挥发 酚去除率均较低。当太阳光Fenton氧化过程H。()2用量为22．5％理论投加量时，采用太阳光Fenton氧化一生化法联合工艺可使煤气含酚 废水的COD由1357mg／L降低至104mg／L，挥发酚由198．2mg／L降低至0．47mg／L，COD和挥发酚均达到国家二级排放标准。 关键词：太阳光； Fenton试剂； 含酚废水； 氧化预处理； 生物降解性 中图分类号：X703．1 文献标志码：A 文章编号：1003-6504(2008)07—0116—04 Effect of Solar Photo-Fenton Preoxidation on Biodegradability of Phenolic Wastewater UU Qiong-yu。 LIU Li， CUI Fei-fei (School of Chemistry and Environmental Engineering，Jianghan University，Wuhan 430056，China) Abstracts：Effect of solar photo—Fenton preoxidation on biodegradability of phenolic wastewater and treatment efficiency of coal gas phenolic wastewater by combined process of solar photo—Fenton biological oxidation were studied．Resul~ showed that both coal gas phenolic wastewater and simulated phenolic wastewater ale biorecalcitrant．Solar photo-Fenton preoxidation is effective at enhancing the biodegradability of phenolic wastewater，and biodegradability of phenolic wastewater enhanced obviously with increasing dosage of H202．The removal efficiency of COD and phenol are low by direct biological oxidation When H202 added only 22．5％ of stoichiometric calculated quantities．COD concentration will reduce from 1，357mg／L tO 104mg／L and phenol reduced from 198．2mg／L to 0，47mg／L，Both COD and phenol in coal gas phenolic wastewater Can satisfy nailonal standard