ABS材料人工加速老化与户外自然老化的相关性.pdfVIP

第 44 卷，第 11 期 工 程 塑 料 应 用 Vol.44 ，No.11 85 2016 年 11 月 ENGINEERING PLASTICS APPLICATION Nov. 2016 doi:10.3969/j.issn.1001-3539.2016.11.019 ABS 材料人工加速老化与户外自然老化的相关性* 王玉海，石光，杨丽庭 ( 华南师范大学化学与环境学院，广州 510006) 摘要：通过红外光谱、色差和力学性能等研究了丙烯腈– 丁二烯– 苯乙烯塑料(ABS) 在人工加速老化试验(UVA ， UVB 和氙灯) 及户外自然老化试验过程中老化行为的相关性。红外分析结果表明，不同ABS 材料在人工加速老化 和自然老化过程中遵循相同的光氧老化动力学，但不同光源对ABS 材料的加速老化作用有明显差别；色差分析结果 表明，人工加速老化试验对色差变化的加速倍率由大到小顺序为：UVB UVA 氙灯。通过分析ABS 材料的色差及 力学性能在人工加速老化与户外自然老化过程中变化的相关性，拟合了人工加速老化与户外自然老化的时间换算方 程。 关键词：丙烯腈– 丁二烯– 苯乙烯塑料；人工加速老化试验；自然老化试验；相关性 中图分类号：TQ325 文献标识码：A 文章编号：1001-3539(2016)11-0085-07 Relationship Between Artificial Accelerated Weathering and Outdoor Natural Weathering for ABS Resin Wang Yuhai ， Shi Guang ， Yang Liting (School of Chemistry and Environment ， South China Normal University ， Guangzhou 510006 ， China) Abstract ：The relationship between the aging behavior of acrylonitrile-butadiene-styrene plastics (ABS) resins in different artificial accelerated weathering tests (UVA ，UVB and xenon) and that in outdoor natural weathering test was investigated by FT–IR ，color aberration and mechanical performance measurements. FT–IR results indicated that the photo-oxidative degradation mechanism of ABS in artificial accelerated weathering tests was the same as that in outdoor natural weathering test. However ， different accelerated weathering test had obvious effect on the accelerated degradation rate of ABS resins. The order of accelerated rate of color aberration by accelerated weathering test was ：UVB UVA xenon. The relationship between artificial accelerat