大气中的氢气记录,Mawson,南极洲(Atmospheric hydrogen record from Mawson, Antarctica).pdf

大气中的氢气记录,Mawson,南极洲(Atmospheric hydrogen record from Mawson, Antarctica) 数据介绍： The listed data have been obtained from flask air samples returned to the CSIRO GASLAB for analysis. Typical sample storage times range from days to weeks for some sites (e.g., Cape Grim) to as much as one year for Macquarie Island and the Antarctic sites. Experiments carried out to test for any change in sample H2 mixing ratio during storage have shown no consistent and systematic drift in these flask types over test periods of several months to years (Cooper et al., 1999). 关键词： 数据格式： TEXT 数据详细介绍： Atmospheric hydrogen record from Mawson, Antarctica L.P. Steele, P.B. Krummel and R.L. Langenfelds Commonwealth Scientific and Industrial Research Organization (CSIRO), Atmospheric Research, Aspendale, Victoria, Australia, 3195 Period of Record February 1992 - December 2001 Methods The listed data have been obtained from flask air samples returned to the CSIRO GASLAB for analysis. Typical sample storage times range from days to weeks for some sites (e.g., Cape Grim) to as much as one year for Macquarie Island and the Antarctic sites. Experiments carried out to test for any change in sample H2 mixing ratio during storage have shown no consistent and systematic drift in these flask types over test periods of several months to years (Cooper et al., 1999). Samples were analyzed by gas chromatography with a mercuric oxide reduction gas detector. H2 reduces HgO to Hg vapor which is detected by UV absorption. One Trace Analytical gas chromatograph, labeled RGA3-1 (R1), was used over the length of the record. Further details of CSIROs global sampling network, sampling, and analytical techniques are provided by Francey et al. (1996); measurement uncertainty is discussed by Langenfelds et al. (2001). Data are reported in the CSIRO94 H2 scale which was defined by dilution of high purity H2 and CH4 (in a 1:3 ratio) with zero air to pro