优化裂解原料的初步研究.pdfVIP

石 油 化 工 0 · 8· PE|TR0CHEMICAL TECHN0L0GY 2008年第37卷第1期 一发一 一开一 一与一 一究一 ～研一 优化裂解原料的初步研究 张兆斌，王国清，张永刚，许士兴 (中国石油化工股份有限公司北京化工研究院，北京 100013) [摘要]利用芳烃抽提、分子筛脱蜡等方法改进裂解原料，并对F—T合成馏分油的裂解性能进行了初步研究。采用芳烃抽提方法 处理原料，提高了原料中烷烃的含量，在裂解条件和乙烯产量相同的条件下，可以节省裂解原料16％以上；而采用5A分子筛对原 料进行脱蜡处理，可以使原料中正构烷烃的含量大大提高，在更为缓和的裂解条件下，乙烯产量相同时，可节省裂解原料50％以 上。F—T合成馏分油以正构烷烃为主，是一种很好的裂解原料。F—T合成馏分油与常规裂解原料相比，在更为缓和的裂解条件下， 可以得到更高的乙烯、丙烯和丁二烯收率。 [关键词]裂解；原料优化；正构烷烃；芳烃抽提；分子筛脱蜡；F—T合成 [文章编号]1000—8144(2008)01—0008—04 [中图分类号]TQ 221．2 [文献标识码]A Elementary Study of Steam Cracking Feedstock Optimization Zhang Zhaobin，Wang Guoqing，Zhang Yonggang，Xu Shixing (Beijing Research Institute of Chemical Industry，SINOPEC，Bering 100013，China) [Abstract]Steam cracking performance of aromatic extracted naphtha，5A molecular sieve dewaxing treated naphtha and F—T synthesis oil had been studied．On the basis of salile ethylene production capacity and same process parameters，taking aromatic extracted naphtha as feed，more than 1 6％ of feed can be saved in comparing with straight—run naphtha．Similarly，on the basis of salile ethylene production capacity and even under more mild steam cracking conditions，taking 5 A molecular sieve dewaxing treated naphtha as feed，more than 50％ of feed Can be saved，due to increase of norm al— paraffin content in the feed in comparing with straight—run naphtha．The main composition of F—T synthesis oils is norm al—paraffin．Their good steam cracking perform ance is as expected． Comparing with straight—run naphtha and straight—run atmospheric gas oil，steam cracking of naphtha and atmospheric gas oil from F—T synthesis achieves higher yields of ethylene