竹叶叶绿素铁钠的制备及性质研究-林产化学与工业.PDF

25 3 Vo.l 25No. 3 2005 9 Chemistry and Industry ofForestProducts Sept. 2005 * 王立娟, 钱学仁 (东北林业大学生物质材料科学与技术教育部重点实验室, 黑龙江 尔滨 150040) : 利用竹材加工的废弃物制取纯天然水溶性绿色素 叶绿素铁钠,并对制备该色素 的两 个主要工序 皂化铁代的最优条件及该色素的稳定性进行了研究试验表明,用 5% NaOH 溶液,在 70 加热 60m in为叶绿素皂化的最佳条件, 然后将皂化溶液的 pH值调为 3. 0, ANG L J 水浴温度为 60 ,铁代处理 60m in时铁代反应最完全所制得的叶绿素铁钠在 pH 值为 3. 0 ~ 6. 0稳定性较好,对室内光热还原剂均有较好的稳定性试验结果表明, 以竹叶为原料制取的叶绿素铁 钠确为一种优良的天然食用绿色素 : 竹叶;叶绿素; 叶绿素铁钠 : TQ611. 5; TQ91 :A : 0253- 2417(2005) 03- 0089- 04 STUDY ON PREPARATION AND CHARACTERISTICSOF SUDIUMIRONCHLOROPHYLLIN FROM BAMBOO LEAVES ANG Lijuan, QIAN Xueren (K ey Laboratory of B iobasedM aterialScience and Technology(NortheastForestry University), M inistry of Education, arbin 150040, China) A bstrac t: Naturalwatersoluble green pigment named sodiumironchlorophyllinwas prepared from bamboo leaves which isakind ofwaste in bambooprocessing. Two key preparationprocesses saponification and iron substitution reaction and the stabilityof the pigmentwere investigated. Itwasfoundthat optmi um conditionsof saponificationwere sodium hydroxide5% and temperature 70 for 60 min. At pH value 3. 0, temperature of water bath 60 for 60m in, a high proportion of sodiumironchlorophyllinwasobtained. ThepH value in the range of 3. 0- 6. 0 had no effect on stability of sodiumironchlorophyllin obtained and itwas stableagainst heat, room light and reducing agent. The results showed that sodiumironchlorophyllin from bamboo leaves is a kind of excellent natural edible green pigment. K ey w ord s: bamboo leave