conductometric studies of thermodynamics of complexation of co2+, ni2+, cu2+, and zn2+ cations with aza-18-crown-6 in binary acetonitrile-methanol mixtures电导的热力学研究络合的co2 + ni2 +,cu2 +,zn2 +阳离子与二进制aza-18-crown-6 acetonitrile-methanol混合物.pdfVIP

Hindawi Publishing Corporation Journal of Thermodynamics Volume 2012, Article ID 109132, 10 pages doi:10.1155/2012/109132 Research Article Conductometric Studies of Thermodynamics of Complexation of Co2+, Ni2+, Cu2+, and Zn2+ Cations with Aza-18-crown-6 in Binary Acetonitrile-Methanol Mixtures Mehdi Taghdiri, Mahmood Payehghadr, Reza Behjatmanesh-Ardakani, and Homa Gha’ari Department of Chemistry, Payame Noor University, P.O. Box 19395-3697, Tehran, Iran Correspondence should be addressed to Mehdi Taghdiri, mehditaghdiri@ Received 2 August 2012; Revised 16 October 2012; Accepted 16 October 2012 Academic Editor: Perla B. Balbuena Copyright © 2012 Mehdi Taghdiri et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The complexation reactions between aza-18-crown-6 (A18C6) and Co2+ , Ni2+ , Cu2+ , and Zn2+ ions were studied conductometri- cally in different acetonitrile-methanol mixtures at various temperatures. The formation constants of the resulting 1 : 1 complexes were calculated from the computer fitting of the molar conductance-mole ratio data at different temperatures. Selectivity of A18C6 2+ 2+ 2+ 2+ ◦ for Co , Ni , Cu , and Zn cations is sensitive to the solvent composition. At 20 C and in acetonitrile solvent, the stability of the resulting complexes varied in the order Zn2+ Cu2+ Co2+ ∼ Ni2+ but the order was reversed by adding 20% methanol. The enthalpy and entropy changes of the complexation reactions were evaluated from the temperature dependence of formation constants. It was found tha