buffer standards for the physiological ph of the zwitterionic buffer 3-[n-tris(hydroxymethyl)methylamino]-2-hydroxypropanesulfonic acid (tapso) from (278.15 to 328.15) k英文论文.pdfVIP

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buffer standards for the physiological ph of the zwitterionic buffer 3-[n-tris(hydroxymethyl)methylamino]-2-hydroxypropanesulfonic acid (tapso) from (278.15 to 328.15) k英文论文.pdf

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buffer standards for the physiological ph of the zwitterionic buffer 3-[n-tris(hydroxymethyl)methylamino]-2-hydroxypropanesulfonic acid (tapso) from (278.15 to 328.15) k英文论文

Vol.2, No.4, 414-421 (2011) Journal of Biophysical Chemistry doi:10.4236/jbpc.2011.24048 Buffer standards for the physiological pH of the zwitterionic buffer 3-[N-tris(hydroxymethyl)methylamino]-2-hydroxypropan esulfonic acid (TAPSO) from (278.15 to 328.15) K * Lakshmi N. Roy, Rabindra N. Roy , Blake M. Bodendorfer, Zachary M. Downs, Stephen D. Rocchio, Jessica M. Stegner, Isaac B. Henson * Hoffman Department of Chemistry, Drury University, Springfield, USA; Corresponding Author: rroy@ Received 22 June 2011; revised 3 August 2011; accepted 24 August 2011. ABSTRACT values of 3-(N-morpholino)-2-hydroxypropanesulfonic acid (MOPSO) [3] from (278.15 to 328.15) K, including The second dissociation constant, pK , and re- 2 310.15 K. The zwitterionic buffer 3-[N,N-bis(2-hydroxy- lated thermodynamic quantities for TAPSO have methyl)amino]-2-hydroxypropanesulfonic acid (DIPSO) been previously determined and reported from [4] is also recommended for physiological use at (278.15 the temperatures (278.15 to 328.15) K. In the to 328.15) K. Regarding the current experiment the goal current study there are five buffer solutions of the authors is to provide staunch pH values for the without NaCl and fiv