chemical analysis through cl-detection assisted by periodate oxidation化学分析通过cl-detection辅助高碘酸盐氧化.pdfVIP

Hindawi Publishing Corporation Bioinorganic Chemistry and Applications Volume 2007, Article ID 92595, 10 pages doi:10.1155/2007/92595 Review Article Chemical Analysis through CL-Detection Assisted by Periodate Oxidation Nicholaos P. Evmiridis, Athanasios G. Vlessidis, and Nicholas C. Thanasoulias Laboratory of Analytical Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece Received 21 September 2006; Revised 14 December 2006; Accepted 29 January 2007 Recommended by Igor O. Fritsky The progress of the research work of the author and his colleagues on the field of CL-emission generated by pyrogallol oxida- tion and further application for the direct determination of periodate and indirect or direct determination of other compounds through flow-injection manifold/CL-detection set up is described. The instrumentation used for these studies was a simple flow- injection manifold that provides good reproducibility, coupled to a red sensitive photomultiplier that gives sensitive CL-detection. In addition, recent reports on studies and analytical methods based on CL-emission generated by periodate oxidation by other authors are included. Copyright © 2007 Nicholaos P. Evmiridis et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. 1. INTRODUCTION emission when are activated from the oxidation reaction. If the activated species have very low quantum yield either be- During a chemical reaction process, the reactant atoms are