原创力文档circular dichroism and derivative spectra study of the excitonic aggregation of pinacyanol by aerosol-ot圆二色性和导数光谱aerosol-ot pinacyanol激子的聚合的研究.pdfVIP
- 1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
- 2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击 这里二次下载。
- 3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
- 4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
- 5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
- 6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
- 7、VIP文档为合作方或网友上传，每下载1次， 网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档
查看更多
circular dichroism and derivative spectra study of the excitonic aggregation of pinacyanol by aerosol-ot圆二色性和导数光谱aerosol-ot pinacyanol激子的聚合的研究
Open Journal of Physical Chemistry , 2012, 2, 34-40
/10.4236/ojpc.2012.21005 Published Online February 2012 (http://www.SciRP.org/journal/ojpc)
Circular Dichroism and Derivative Spectra Study of the
Excitonic Aggregation of Pinacyanol by Aerosol-OT
Sa’ib J. Khouri1*, Volker Buss2
1Department of Chemistry, American University of Madaba, Madaba, Jordan
2Fachbereich Chemie, Universität Duisburg-Essen, Essen, Germany
*
Email: sbkhouri@
Received August 8, 2011; revised August 31, 2011; accepted October 25, 2011
ABSTRACT
Different structures are proposed for the complexes formed from the interaction between the cationic cyanine dye 1,
1’-diethyl-2, 2’-carbocyanine chloride (Pinacyanol chloride) and the anionic surfactant sodium bis (2-ethylhexyl) sul-
fosuccinate (Aerosol-OT) in ethanol-water solutions. UV/vis and electronic circular dichroism (CD) spectra provide
tools to study the concentration and solvent dependence of this interaction. The aggregation spectra of the dye are
dominated by a strongly blue-shifted, sharp and single visible band, which appears at concentrations much below the
critical micelle concentration (cmc) of Aerosol-OT. Above the cmc, the spectra in pure aqueous solution indicate disso-
ciation into monomer and dimer species, and the system becomes completely empty of chirality. Two different CD
spectra with a distinct isosbestic point are observed for complexes with different surfactant to dye ratios. Both the addi-
tion of ethanol (more than 7.5%) and increasing the temperature retards the metachromatic process between the dye and
Aerosol-OT. By using the pea
您可能关注的文档
- change in stature by walking and running at a preferred transition speed改变身材的行走和奔跑速度优先过渡.pdf
- changes in eeg power spectral density and cortical connectivity in healthy and tetraplegic patients during a motor imagery task脑电图功率谱密度的变化和皮层连接在健康和瘫痪患者患者在运动图像的任务.pdf
- changes in body composition of women at different age decades and its relation with to metabolic risks身体成分的变化在不同年龄的女性,与代谢风险的关系.pdf
- chance-constrained approaches for multiobjective stochastic linear programming problems机会约束多目标随机线性规划问题的方法.pdf
- changes in land use, socioeconomic indices, and the transportation system in gifu city and their relevance during the late 20th century土地利用的变化,社会经济指标,和交通系统在岐阜市及其相关性在20世纪末.pdf
- changes in a2a adenosine receptor parameters in patients affected by bipolar disorders correlation with antipsychotic dosage and severity of illness负责腺苷受体的变化参数影响双相情感障碍患者与抗精神病药物的剂量和严重程度相关性疾病.pdf
- changes in excitability of the motor cortex associated with internal model formation during intrinsic visuomotor learning in the upper arm兴奋性的变化与内部模型相关的运动皮层形成内在visuomotor学习中上臂.pdf
- changes in erythrocyte sedimentation rate, white blood cell count, liver enzymes, and magnesium after gastric bypass surgery红细胞沉降率的变化、白细胞计数、肝酶和胃旁路手术后镁.pdf
- changes in lipids and lipoproteins after selective ldl apheresis (7-year experience)脂质和脂蛋白的变化后,选择性低密度脂蛋白apheresis(7年经验).pdf
- changes in mangrove epifaunal assemblages caused by forest logging during hunting of the neotropical cormorant (phalacrocorax brasilianus) on the colombian pacific coast红树林epifaunal组合的变化在狩猎的热带森林砍伐造成的鸬鹚(phalacrocorax brasilianus)在哥伦比亚太平洋沿岸.pdf
- circulating immune complexes among diabetic children循环免疫复合物在糖尿病的孩子.pdf
- claisen and intermolecular rearrangement of cinnamyloxynaphthalenes克莱森和cinnamyloxynaphthalenes分子间重排.pdf
- city routing velocity estimation model under theenvironment of lack of floating car data城市路由速度估计模型的环境下缺乏浮动车数据.pdf
- circulating tumor cell analysis technical and statistical considerations for application to the clinic循环肿瘤细胞分析技术和统计考虑应用到诊所.pdf
- clarifying the language of chance using basic conditional probability reasoning the monty hall problem澄清的机会的语言使用基本条件概率推理monty hall的问题.pdf
- circulating tumor cells measurements in hepatocellular carcinoma循环肿瘤细胞在肝细胞癌测量.pdf
- classical derivation of auxiliary lorentz transforms their relations with special relativity古典辅助洛伦兹变换的推导与狭义相对论的关系.pdf
- class of service support layer for wireless mesh networks类的服务支持层无线网状网络.pdf
- circumcision with the plastibell device in hooded prepuce or glanular hypospadias包皮环切术与plastibell设备在连帽包皮或glanular尿道下裂.pdf
- circular polya distributions of order圆形玻利亚分布律.pdf
文档评论（0）