原创力文档crystalline manganese carbonate a green catalyst for biodiesel production生物柴油生产结晶碳酸锰的绿色催化剂.pdfVIP
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crystalline manganese carbonate a green catalyst for biodiesel production生物柴油生产结晶碳酸锰的绿色催化剂
Green and Sustainable Chemistry, 2012, 2, 14-20
/10.4236/gsc.2012.21003 Published Online February 2012 (http://www.SciRP.org/journal/gsc)
Crystalline Manganese Carbonate a Green Catalyst for
Biodiesel Production
1 2 1
Yerraguntla Rajeshwer Rao , Pudukulathan Kader Zubaidha , Jakku Narender Reddy ,
2 2
Dasharath Dattatraya Kondhare , Deshmukh Shivagi Sushma
1Department of Chemistry, Govt. City College, Hyderabad, India
2School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, India
Email: yrajeshwer@
Received December 19, 2011; revised January 26, 2012; accepted February 7, 2012
ABSTRACT
Crystalline manganese carbonate was found to be a versatile green, non corrosive and environmental friendly catalyst
for transesterification of vegetable oils. Its use as catalyst in the transesterification process involving methanol and
vegetable oils (palm, rapeseed, groundnut, coconut and caster oils) resulted in a conversion rate of 80% - 95% in the
production of biodiesel. The chemical composition of the obtained biodiesel was studied by GC-MS analysis and
showed the presence of linoleic, oleic, palmitic, and stearic acids methyl esters to be the major compounds. Manganese
carbonate in comparison with other solid catalysts was found to decrease the reaction time and temperature concomitant
with an increase of biodiesel yield. Finally, the effect of various parameters including methanol quantity
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