determination of external mass transfer model for hydrolysis of jatropha oil using immobilized lipase in recirculated packed-bed reactor确定外部质量传递模型中使用固定化脂肪酶水解的麻疯树油循环填充床反应器.pdfVIP
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determination of external mass transfer model for hydrolysis of jatropha oil using immobilized lipase in recirculated packed-bed reactor确定外部质量传递模型中使用固定化脂肪酶水解的麻疯树油循环填充床反应器
Advances in Chemical Engineering and Science, 2011, 1, 289-298
doi:10.4236/aces.2011.14040 Published Online October 2011 (http://www.SciRP.org/journal/aces)
Determination of External Mass Transfer Model for
Hydrolysis of Jatropha Oil Using Immobilized Lipase in
Recirculated Packed-Bed Reactor
1 1 2 1*
Chong-Wan Cheng , Rahmath Abdulla , Rao Rampally Sridhar , Pogaku Ravindra
1School of Engineering and Information Technology, University Malaysia Sabah, Kota Kinabalu, Malaysia
2Chemical Engineering Department, Chaitanya Bharathi Institute of Technology, Hyderabad, India
*
E-mail : dr_ravindra@
Received August 11, 2011; revised August 26, 2011; accepted October 4, 2011
Abstract
In this study, a simple and effective technique for establishing an external mass transfer model in a recircu-
lated packed-bed batch reactor (RPBBR) with an immobilized lipase enzyme and Jatropha oil system is pre-
sented. The external mass transfer effect can be represented with a model in the form of Colburn factor JD =
K Re–(1–n) . The value of K and n were derived from experimental data at different mass flow rates.The ex-
periment shows an average increment of 1.51% FFA for calcium alginate and 1.62% FFA for carrageenan
after the hydrolysis took place. Based on different biopolymer material used in immobilized beads, JD =
–0.4 –0.3
1.674 Re for calcium alginate and J = 1.881 Re for k-carrageenan were found to be adequate to predict
D
the experimental data for external mass transfe
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