低浓度甲醛水溶液的气液平衡体系研究-南京大学学报（自然科学）.PDF

( ) 46 5 V o l. 46, No. 5 JOU R NA L OF NA NJIN G U N IV ERSIT Y 2010 9 Sep .2010 ( NAT U RA L SCIEN CES) * ** 金凯洪, 郭亚红, 张 晶, 李雪茹, 李 磊 , 张志炳 ( , , 210093) : , , ( 1% ) . . W ilson - , , . . : , , : O 64242 Research on the vaporliquid equilibrium system of formaldehyde aqueous solution with low concentration Jin K aiH ong, Guo YaH ong, Zhang J ing, L i X ueRu, L i Lei, Zhang ZhiBing ( Scho ol of Chemis ry and Chmeical Enigeering , N anjing U niver si y, N anj ing, 210093, China) Abstract: By he vaporliquid equilibrium measur ing device, he vaporliquid equilibrium parame er s o f forma ldehy de aqueou s solu ion w i h low w eigh co ncen ra ion of below 1% w as measured under hig h pressur es for he f irs ime. T he aver ag e value of r ela ive vo la ili y fo r he for maldehy de so lu io n w i h lo w co ncen ra ion , w hich w as calcula ed by he ex per imen a l da a, is very close o he r epo r ed o ne for fo rmaldehyde aqueo us so lu io n w i h higher co ncen ra ions. T he vaporliquid equilibr ium par ame er of fo rmaldehyde solu ion w i h low concen r a io n w as heo re ically calcula ed by he sa ur a ed vapor pressure me ho d and Wilson model, and compared w i h he ex perimen al da a. T he li le r ela iv e dev ia ion be w een hem has v erif ied he au hen ici y and r eliabili y o f he ex perimen al da a. T he v apo rliquid equilibrium parame ers o b