第六章光度法（The sixth chapter photometric method）.docVIP

第六章光度法（The sixth chapter photometric method） The sixth chapter is the absorption spectrophotometry (advanced pharmaceutical analysis and laboratory analysis of theoretical papers) Fill in the blanks (1 points, 20 points each) 1, the ultraviolet visible absorption spectrum is produced by the transition of the valence electron in the molecule. 2, different wavelengths of light have different energies. The greater the wavelength, the smaller the energy of the light??????????? 3. Compared with the atomic absorption spectra, the molecular absorption spectra are band spectra 4. The color of matter is produced by the selective absorption of matter to different wavelengths of light. The color of copper sulfate is blue because it absorbs the yellow light in white light.????? 5. Two. The carbon tetrachloride extractant absorbs light from 580 to 620nm wavelengths. Therefore, the color of the extractant is blue, and 6, and the molar absorption coefficient is L mol-1 cm-1? 7, the same quality of A, B two material, its molar mass M (A) M (B), after the same way of color determination, the measured absorbance is equal, then their molar absorption coefficient is the relationship between? 8. The molar concentration of a colored substance is 1 * 10-5mol/L. The absorbance at the maximum absorption wavelength of 1cm cuvette is 0.28. At this wavelength, the molar absorption coefficient of the colored object is 2.8 * 10-4mol/L?????????????????????????????????????????????????????????????????????????????????????????????????????????????? 9. The relation between absorbance A and transmittance T is -lgT=A???????? 10. When the iron content was 1 x 10-4mol/L, the transmittance was 64%. If the concentration was 1.5 * 10-4mol/L, the transmittance was two????????? 0.512??? 11, the theoretical value of the corresponding slope S (mv/px) of the ion selective electrode is? 12. The wavelength range of visible light visible to the human eye is 400~760nm??????????????????????. 13. In ultraviolet visible