Aromaticity of Phosphorus Heterocycles-[Nyulaszi L ]化学.pdf

Chem. Rev. 2001, 101, 1229−1246 1229 Aromaticity of Phosphorus Heterocycles La´szlo´ Nyula´szi* Department of Inorganic Chemistry, Budapest University of Technology and Economics, H-1521 Budapest, Gelle´rt te´r 4, Hungary Received September 11, 2000 Contents I. Scope, Time Frame 1229 II. Introduction 1230 III. “A”-Type Bonding, PC Bond in Aromatic 1230 Systems A. Three-Membered Ring: Phosphirene Cation 1230 (5) B. Four-Membered Rings 1230 C. Five-Membered Rings 1231 1. Phospholide (6) and Polyphospholide 1231 Anions 2. Heterophospholes 1231 D. Six-Membered Rings 1233 1. Phosphinine (3) 1233 Professor Nyula´szi was born in Budapest and received his M.S. degree 2. Azaphosphinines 1235 at the Technical University of Budapest. He received his doctoral degree 3. Di- and Triphosphinines 1235 at the same institution in 1986 and became a staff member there. In 4. Hexaphosphinine (P6) 1236 1990 he visited the photoelectron spectroscopic research group of