原创力文档a new method to determine the anaerobic degradability of surfactants the anbusdic test一个新的方法来确定表面活性剂的厌氧降解性anbusdic测试.pdfVIP
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a new method to determine the anaerobic degradability of surfactants the anbusdic test一个新的方法来确定表面活性剂的厌氧降解性anbusdic测试
Bendt and Willing Environmental Sciences Europe 2012, 24:38
/content/24/1/38
RESEARCH Open Access
A new method to determine the anaerobic
degradability of surfactants: the AnBUSDiC test
Thomas Bendt 1 and Andreas Willing2*
Abstract
Background: Surfactants are chemicals with a high production volume and a wide dispersive use, i.e. surfactants
have a high environmental impact. Most commercial surfactants are aerobically biodegradable. Only a small fraction
of the surfactants is not aerobically broken down during the usual hydraulic retention times of modern WWTPs.
This fraction, due to the predominantly hydrophobic nature of surfactants, adheres to the sludge. The sludge is
usually collected and further treated under anaerobic conditions in digester tanks. Therefore, the knowledge about
anaerobic biodegradability under digester tank conditions is important to gain an understanding about the
environmental fate of surfactants.
Results: A new test method suited for the assessment of the anaerobic biodegradability of surfactant under
sewage plant simulation conditions is proposed. The test method foresees that an accurately known amount of the
test substance is added to the sludge inoculum, and that the test substance is added in two sequential steps to
overcome possible interferences from unspecific digester gas formation caused by the surface-activity of the
surfactant test substance. By measuring the difference in the gas volumes produced in the sludge inoculum plus
test substance and the corresponding control (sludge inoculum only) and converting the gas volumes to the
percentage degree of biodegradation, this test allows the quantification of the anaerobic biodegradability of the
test substance.
Conclusions: Tests with commercial surfactants indicate that the newly developed test method allows for a
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