常用溶剂在NMR中的残余峰.doc

NMR of Common Solvent Impurities in CD2Cl2 ? ? 1H NMR 13C NMR CH3COCH3 2.09 (s) 206.6 (s), 30.8 (s) CHCl3 7.32 (s) 77.9 (s) C6H5Cl 7.26-7.37 (m) 134.5 (s), 130.2 (s), 128.9 (s), 126.9 (s) C6H5CH3 7.12-7.26 (m), 2.34 (s) 138.4 (s), 129.4 (s), 128.6 (s), 125.6 (s), 21.6 (s) C6H6 7.36 (s) 128.6 (s) n-Hexane 1.26-1.32 (m), 0.89 (t, 3J = 7.0) 32.1 (s), 23.1 (s), 14.3 (s) n-Pentane 1.24-1.33 (m), 0.89 (t, 3J = 7.0) 34.5 (s), 22.7 (s), 14.2 (s) CH3OH 3.37 (s) 50.2 (s) Et2O 3.44 (q, 3J = 7.0), 1.15 (t, 3J = 7.0) 66.0 (s), 15.5 (s) THF 3.68 (m), 1.82 (m) 68.1 (s), 25.9 (s) H2O 1.53 (s) ? Silicone 0.08 (s) ? Apiezon M 1.26 (s, br), 0.86 (m, br) ? Apiezon N 2.12 (s), 1.26 (m, br), 0.88 (m, br) ? MeCN 1.949 (s) 117.0 PMe3 0.98 (d) C6H5Br 7.50 (d), 7.30 (t), 7.26 (t) C6Me6 2.20 (s)  1H and 13C NMR spectra were recorded at ambient temperature. Chemical shifts are reported relative to SiMe4 and were determined by reference to the residual solvent resonances, 5.32 (t) for 1H and 53.8 (quint) for 13C, respectively. All coupling constants are given in Hertz. ? NMR of Common Solvent Impurities in C6D5Cl ? ? 1H NMR 13C NMR CH2Cl2 4.78 (s) 53.4 (s) CH3COCH3 1.78 (s) 204.3 (s), 30.1 (s) CHCl3 6.74 (s) 77.4 (s) C6H5CH3 6.95-7.19 (m), 2.18 (s) 137.8 (s), 129.2 (s), 128.4 (s), 125.5 (s), 21.4 (s) C6H6 7.22 (s) 128.5 (s) n-Hexane 1.17-1.29 (m), 0.87 (t, 3J = 7.2) 31.9 (s), 23.0 (s), 14.3 (s) n-Pentane 1.13-1.30 (m), 0.86 (t, 3J = 7.2) 34.4 (s), 22.7 (s), 14.2 (s) CH3OH 4.08 (q, 3J = 4.8 ), 3.31 (d, 3J = 4.8) 49.7 (s) Et2O 3.31 (q, 3J = 7.0), 1.11 (t, 3J = 7.0) 65.8 (s), 15.5 (s) THF 3.59 (m), 1.56 (m) 67.7 (s), 25.8 (s) ? H2O 1.06 (s) ? Silicone 0.25 (s) ? Apiezon M 1.77 (s), 1.29 (m, br), 0.91 (m, br) ? Apiezon N 1.78 (s), 1.32 (s, br), 0.90 (m, br) ?  * 1H and 13C NMR spectra were recorded at ambient temperature. Chemical shifts are reported relative to SiMe4 and were determined by reference to the residual solvent resonan