二氧化氯的介绍（Introduction of chlorine dioxide）.docVIP

二氧化氯的介绍（Introduction of chlorine dioxide） Application of chlorine dioxide technology in water treatment 2007-6-12 0:42:14 1 Overview Chlorine dioxide is a new generation of high efficiency, high speed oxidation bactericidal biocide. It has good bactericidal and disinfection properties. Chlorine dioxide is an ideal product in municipal drinking water and wastewater treatment. Compared with chlorine dioxide, chlorine dioxide does not produce three halogenated methane with organic matter in water, and does not react with ammonia nitrogen, nor does it produce chlorinated amines, but it can destroy phenols, sulfides, cyanide and many other organic compounds. Compared with ozone, chlorine dioxide process has less investment, higher yield, longer residence time in water, and can effectively kill and control various bacteria. At the same time, chlorine dioxide will not react with bromate or bromate in water to produce substances harmful to human body. 2 Properties of chlorine dioxide Chlorine dioxide exists in the form of gas at room temperature and can also be liquid at low temperature. The solubility of gas in water is 2.9g/l (22 DEG C). Chlorine dioxide exists in the presence of free radical, and chlorine and oxygen bonds exhibit obvious double bond characteristics. The O-Cl-O bond has a key angle of 117.5 degrees and a bond length of 1.47 * 10-10m. Chlorine dioxide has a conjugated structure because the 3d orbitals of chlorine can participate in the conjugation of C- PI bonds. There is tetravalent to chlorine dioxide, its activity is 2.5 times that of chlorine, chlorine chlorine content is 100%, the effective chlorine content of chlorine dioxide is 263%. Liquid chlorine dioxide is extremely unstable, and light, mechanical collisions, or exposure to organic matter can all explode. When the content of gaseous chlorine dioxide is higher than 10% in the air, it is extremely explosive when exposed to Mars, which is very safe only in solution. The redox capacity of chlorine d