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酯化反应除水(Esterification; water removal)
酯化反应除水(Esterification; water removal)
Question: how can an esterification remove water?
Category: ask for help (reward points: 3 points)
Question: Ziwei
Grade: 3
Questions about Organic Chemistry (fpcwin1211, netpanda, yjgzfl, Ftian, etc.)
Credit: 47%
Reply: 30
Reading: 1682
Time: 2006-07-25, 14:25:55 editor, add / cancel, collect custom / cancel SMS, report it
--------------------------------------------------------------------------------
Acid reaction of macromolecule alcohols and small molecules. What is the simple way to remove water from this esterification reaction? Is it possible to boil off the mixture without organic solvent? Can I just add a water separator? You look generous with your criticism
Answer: generalsss, 14:48:17: 2006-07-25) (long time editor 1 floor
The oil separator is theoretically possible. But it depends on the density of your stuff!
Answer: Edwin, * * (Bao Jianfeng from sharpening out, plum flower) time: 2006-07-25 14:52:36 Editor 2 floor
This depends on the specific circumstances. Because you are a big molecule of alcohol, so I guess the boiling point is very high, not thinking about it. But if the small molecule acid, distilled water, easy steamed, and small molecule acids are generally soluble in water, water separator is not like you. In this case, I think it is better to use anhydride reaction, reaction speed, and side reactions are less. Because of the small molecule acid anhydride is relatively easy to get
Answer: gljfun, 14:55:14: 2006-07-25) (long time Editor 3 floor
For micro reactions such as milligrams, water and oil separators cannot be used, as water is produced too little. Carbon amine two amines, such as DCC and EDC, can be used as both catalyst and water binding agent.
Answer: Ziwei, 16:15:30: 2006-07-25) (long time editor 4 floor
Thank you, my friends! My ester is less than the density of water. I use methacrylic acid and the boiling point is 185. Edwin friends, the reaction with anhydride will also produce water, is it
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