电感耦合等离子体质谱法测定农产品产地土壤中重金属元素.pdfVIP

· · 228 闵广全等，电感耦合等离子体质谱法测定农产品产地土壤中重金属元素 Vol． 36 ， No． 3 ，2014 电感耦合等离子体质谱法测定农产品产地土壤中重金 属元素 闵广全 （国土资源部沈阳矿产资源监督检测中心 ，辽宁 沈阳 110032） 摘要: 农产品产地土壤样品经 四酸 （盐酸、 硝酸、 氢氟酸和高氯酸） 分解和王水提取后， 采用电感耦合等离子体质谱 （ICP-MS ）法对重金属元素铬、镉和铅进行分析，通过在线加入 内标校正基体效应和接 口效应，应用干扰校正公式消除元素质量 数干扰。 测定元素校正曲线相关系数在 0.9995 以上 ，元素方法检出限（3s ）在0.013~2.33μg.g-1 之间 ，RSD%＜10（n=12 ），加标回 收率在 98.1%~103.4%之间 ，结果令人满意。 关键词 ：电感耦合等离子体质谱法；农产品产地 ；土壤 ；重金属元素 中图分类号：TE 967.18 文献标识码：B 文章编号：1001-0017（2014 ）03-0228-03 Determination of Heavy Metal Elements in Agricultural Soil with ICP-MS Method MIN Guang-quan （Shenyang Mineral Resources Supervision and Inspection Center, Ministry of Land and Resources, Shenyang 110032, China ） Abstract: The agricultural soil samples were decomposed with four acids （hydrochloric acid, nitric acid, hydrofluoric acid and perchloric acid ） and extracted with aqua regia. The heavy metal elements, such as Cr, Cd and Pb were analyzed with ICP-MS method. The matrix effect and interface effect were corrected by the on-line addition of internal standards, and the element mass number interference was eliminated by the correction formula of interference. All the tested elements ’ correlation coefficients were over 0.9995, the detection limits （3s ）of these elements were found in the range from 0.013 to 2.33μg.g-1, RSD%＜10（n=12 ）, and the adding standard recovery was between 98.1% and 103.4%. The results were satisfied. Key words: ICP-MS; agricultural producing area; soil; heavy metal elements 酸、氢氟酸和高氯酸）溶解，王水提取，电感耦合等 前 言 离子体质谱法（ICP-MS ）对土壤样品中重金属元素