利用核磁共振测量乙醇汽油溶液浓度的实验探索-陶保收王旭阳郑权.docxVIP

利用核磁共振测量乙醇汽油溶液浓度的实验探索陶保收，郑权，王旭阳，尼浩（中国石油大学（华东）理学院，山东 青岛 266580）摘 要: 为探索利用核磁共振技术测量乙醇汽油浓度的方法，用无水乙醇和 93#汽油配制出乙醇体积百分数为20% ～100% 的乙醇汽油溶液，利用核磁共振技术测量了不同乙醇含量汽油样品的第二信号峰时间，发现其随乙醇含量的变化不呈现一定规律性的变化。因此，在减小操作误差的基础上加入 CuCl2·2H2O来扩大乙醇含量对核磁共振第二信号峰时间的影响。结果表明: 加入 CuCl2·2H2O可使核磁共振第二信号峰时间随乙醇含量增加而增大，并且呈线性关系。根据实验结果拟合出了核磁共振第二信号峰时间随乙醇含量变化的经验公式，提出了乙醇汽油溶液浓度的核磁共振检测方法，通过实例测量验证了这一方法的有效性和可靠性。关键词: 乙醇汽油; 浓度; 核磁共振; 第二信号峰时间An Experimental Exploration on the NMR Method for Measuring Ehanol Concentration of Ethanol-gasolineTAO Bao-shou,ZHENG Quan,WANG Xu-yang,NI Hao.(Faculty of Science in China University of Petroleum,Qingdao 266580,Shandong.)Abstract:Different nuclear magnetic resonancepeaks of the secondtime of pre-made ethanol-gasoline with ethanol content from 20% to 100% has been measured by using nuclear magnetic resonance ( NMR) method in order to investigate nuclear magnetic resonance (NMR) method for measuring ethanol concentration of ethanol-gasoline．It’s indicated that Nuclear magnetic resonancepeaks of the secondtime doesn’t hold a regular change with the increasing ethanol content． For this reason，CuCl2·2H2O has been used tentatively to expand the influence of ethanol content on nuclear magnetic resonancepeaks of the secondtime in the fundamental of reducing operation errors．The results show that the nuclear magnetic resonancepeaks of the secondtime increases with an increase of ethanol content and it’s a linear relationship between them. Thus，a logarithmic relationship between the nuclear magnetic resonancepeaks of the secondtimeand the ethanol concentration is fittedfrom the experimental dataand an innovative method has been found to measure the ethanol concentration of ethanol-gasolineand the validity and reliability of this method has been verified by the experiments．Key words:ethanol-gasoline;ethanolconcentration;nuclear magnetic resonance ( NMR);nuclear magnetic resonancepeaks of the secondtime .1．引言随着石油资源的匮乏和能源需求量的日益增大及人们环境保护意识的增强，传统石油燃料汽油和柴油的使用面临着极大的挑战，世界各国在不同程度上加紧了对汽车替代燃料和混合燃料的开发和利用