原创力文档assessment of metals bioavailability to vegetables under field conditions using dgt, single extractions and multivariate statistics金属生物利用度的评估使用分析我国蔬菜在田间条件下,单一的抽取和多元统计数据.pdfVIP
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assessment of metals bioavailability to vegetables under field conditions using dgt, single extractions and multivariate statistics金属生物利用度的评估使用分析我国蔬菜在田间条件下,单一的抽取和多元统计数据
Senila et al. Chemistry Central Journal 2012, 6:119
/content/6/1/119
RESEARCH ARTICLE Open Access
Assessment of metals bioavailability to vegetables
under field conditions using DGT, single
extractions and multivariate statistics
*
Marin Senila , Erika Andrea Levei and Lacrimioara Ramona Senila
Abstract
Background: The metals bioavailability in soils is commonly assessed by chemical extractions; however a generally
accepted method is not yet established. In this study, the effectiveness of Diffusive Gradients in Thin-films (DGT)
technique and single extractions in the assessment of metals bioaccumulation in vegetables, and the influence of
soil parameters on phytoavailability were evaluated using multivariate statistics. Soil and plants grown in vegetable
gardens from mining-affected rural areas, NW Romania, were collected and analysed.
Results: Pseudo-total metal content of Cu, Zn and Cd in soil ranged between 17.3-146 mg kg-1, 141–833 mg kg-1
and 0.15-2.05 mg kg-1, respectively, showing enriched contents of these elements. High degrees of metals
extractability in 1M HCl and even in 1M NH4Cl were observed. Despite the relatively high total metal concentrations
in soil, those found in vegetables were comparable to values typically reported for agricultural crops, probably due
to the low concentrations of metals in soil solution (C ) and low effective concentrations (C ), assessed by DGT
soln E
technique. Among the analysed vegetables, the highest metal concentrations were found in carrots roots. By
applying multivariate statistics, it was found that C , C and extraction in 1M NH Cl, were better predictors for
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