new element organic frameworks based on sn, sb, and bi, with permanent porosity and high catalytic activity新元素有机框架基于sn,某人,和bi,永久的孔隙度和高催化活性.pdfVIP

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new element organic frameworks based on sn, sb, and bi, with permanent porosity and high catalytic activity新元素有机框架基于sn,某人,和bi,永久的孔隙度和高催化活性.pdf

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new element organic frameworks based on sn, sb, and bi, with permanent porosity and high catalytic activity新元素有机框架基于sn,某人,和bi,永久的孔隙度和高催化活性

Materials 2010, 3, 2447-2462; doi:10.3390/ma3042447 OPEN ACCESS materials ISSN 1996-1944 /journal/materials Article New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity Julia Fritsch 1, Marcus Rose 1, Philipp Wollmann 1, Winfried Böhlmann 2 and Stefan Kaskel 1,* 1 Department of Inorganic Chemistry, Dresden University of Technology, Mommsenstraße 6, D-01062 Dresden, Germany; E-Mails: julia.fritsch@chemie.tu-dresden.de (J.F.); marcus.rose@chemie.tu-dresden.de (M.R.); philipp.wollmann@chemie.tu-dresden.de (P.W.); 2 Faculty of Physics and Earth Science, University of Leipzig, Linnéstraße 5, D-04103 Leipzig, Germany; E-Mail: bohlmann@physik.uni-leipzig.de (W.B.) * Author to whom correspondence should be addressed; E-Mail: stefan.kaskel@chemie.tu-dresden.de; Tel.: +49-351 Fax: +49-351 Received: 31 January 2010 / Accepted: 25 March 2010 / Published: 30 March 2010 Abstract: We present new element organic frameworks based on Sn, Sb and Bi atoms connected via organic linkers by element-carbon bonds. The open frameworks are characterized by specific surface areas (BET) of up to 445 m2 g-1 and a good stability under ambient conditions resulting from a highly hydrophobic inner surface. They show good performance as heterogeneous catalysts in the cyanosylilation of benzaldehyde as a test reaction. Due to their catalytic activity, this class of material